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Tunable Crystal-to-Crystal Phase Transition in a Cadmium Halide Chain Polymer 英文参考文献
Polymers2011,3,1151-1161;doi:10.3390/polym3031151
OPENACCESS
polymers
ISSN2073-4360
/journal/polymers
Article
TunableCrystal-to-CrystalPhaseTransitioninaCadmium
HalideChainPolymer
KevinLamberts,IrmgardKalf,AmrRamadan,PaulMu¨ller,RichardDronskowskiand
UlliEnglert
?
InstituteofInorganicChemistry,RWTHAachenUniversity,Landoltweg1,52056Aachen,Germany;
E-Mails:kevin.lamberts@rwth-aachen.de(K.L.);irmgard.kalf@ac.rwth-aachen.de(I.K.);
amr.ramadan@rwth-aachen.de(A.R.);paul.mueller@ac.rwth-aachen.de(P.M.);
drons@hal9000.ac.rwth-aachen.de(R.D.)
?
Authortowhomcorrespondenceshouldbeaddressed;E-Mail:ullrich.englert@ac.rwth-aachen.de;
Tel.:+49-241-809-4666;Fax:+49-241-809-2288.
Received:8June2011;inrevisedform:11July2011/Accepted:21July2011/
Published:25July2011
Abstract: Thechainpolymer[{Cd(μ-X)2py2}
1
∞
](X=Cl,Br;py=pyridine)undergoesa
fullyreversiblephasetransitionbetweenamonocliniclow-temperatureandanorthorhombic
high-temperature phase. The transformation can be directly monitored in single crystals
andcanbecon?rmedforthebulkbypowderdiffraction. Thetransitiontemperaturecan
beadjustedbytuningthecompositionofthemixed-halidephase: Transitiontemperatures
between175Kuptothedecompositionofthematerialatca.350Kareaccessible.Elemental
analysis, ion chromatography and site occupancy re?nements from single-crystal X-ray
diffractionagreewithrespecttothestoichiometriccompositionofthesamples.
Keywords: tunable phase transition; crystal-to-crystal transformation; chain polymer;
cadmiumcompounds;X-raypowderdiffraction;single-crystalX-raydiffraction;twinning;
ionchromatography
1. Introduction
Coordinationpolymersandinorganic-organichybridmaterialsfeatureaplethoraoftopologies,and
theyoftenshowintriguingproperties. Overthelastdecade,ourgrouphasdevotedsystematicstudies
Polymers2011,3
1152
to halide-bridged polymers of divalent cations; the subject has recently been reviewed [1]. Several
compoundsinthisclassundergosingle-crystaltosingle-crystaltransformations: Wehaveencountered
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