Tunable Crystal-to-Crystal Phase Transition in a Cadmium Halide Chain Polymer 英文参考文献.docVIP

Tunable Crystal-to-Crystal Phase Transition in a Cadmium Halide Chain Polymer 英文参考文献.doc

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Tunable Crystal-to-Crystal Phase Transition in a Cadmium Halide Chain Polymer 英文参考文献

Polymers2011,3,1151-1161;doi:10.3390/polym3031151 OPENACCESS polymers ISSN2073-4360 /journal/polymers Article TunableCrystal-to-CrystalPhaseTransitioninaCadmium HalideChainPolymer KevinLamberts,IrmgardKalf,AmrRamadan,PaulMu¨ller,RichardDronskowskiand UlliEnglert ? InstituteofInorganicChemistry,RWTHAachenUniversity,Landoltweg1,52056Aachen,Germany; E-Mails:kevin.lamberts@rwth-aachen.de(K.L.);irmgard.kalf@ac.rwth-aachen.de(I.K.); amr.ramadan@rwth-aachen.de(A.R.);paul.mueller@ac.rwth-aachen.de(P.M.); drons@hal9000.ac.rwth-aachen.de(R.D.) ? Authortowhomcorrespondenceshouldbeaddressed;E-Mail:ullrich.englert@ac.rwth-aachen.de; Tel.:+49-241-809-4666;Fax:+49-241-809-2288. Received:8June2011;inrevisedform:11July2011/Accepted:21July2011/ Published:25July2011 Abstract: Thechainpolymer[{Cd(μ-X)2py2} 1 ∞ ](X=Cl,Br;py=pyridine)undergoesa fullyreversiblephasetransitionbetweenamonocliniclow-temperatureandanorthorhombic high-temperature phase. The transformation can be directly monitored in single crystals andcanbecon?rmedforthebulkbypowderdiffraction. Thetransitiontemperaturecan beadjustedbytuningthecompositionofthemixed-halidephase: Transitiontemperatures between175Kuptothedecompositionofthematerialatca.350Kareaccessible.Elemental analysis, ion chromatography and site occupancy re?nements from single-crystal X-ray diffractionagreewithrespecttothestoichiometriccompositionofthesamples. Keywords: tunable phase transition; crystal-to-crystal transformation; chain polymer; cadmiumcompounds;X-raypowderdiffraction;single-crystalX-raydiffraction;twinning; ionchromatography 1. Introduction Coordinationpolymersandinorganic-organichybridmaterialsfeatureaplethoraoftopologies,and theyoftenshowintriguingproperties. Overthelastdecade,ourgrouphasdevotedsystematicstudies Polymers2011,3 1152 to halide-bridged polymers of divalent cations; the subject has recently been reviewed [1]. Several compoundsinthisclassundergosingle-crystaltosingle-crystaltransformations: Wehaveencountered

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