Vibrational Spectra Study of the Interactions Between Keggin Heteropolyanions and Amino Acids 英文参考文献.docVIP

Molecules 2009, 14, 3214-3221; doi:10.3390/moleculeOPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article Vibrational Spectra Study of the Interactions Between Keggin Heteropolyanions and Amino Acids Fatemeh F. Bamoharram Department of Chemistry, Islamic Azad University, Mashhad -Branch, Mashhad, Iran; E-mails: abamoharram@ or fbamoharram@mshdiau.ac.ir Received: 24 June 2009; in revised form: 17 August 2009 / Accepted: 19 August 2009 / Published: 27 August 2009 Abstract: A study of the effects of the interactions with amino acids on the vibrational spectra of Keggin heteropolyanions (NanH3-n[XM12O40]n-; n = 0,1,2,3; X = PV, SiIV, M = WVI, MoVI) has been performed. Interactions occurred for all of the studied compounds leading to changes and splits in the stretching frequencies. Depending on the amino acid type, the IR bands for interbridge stretchings (M-Ob-M) and terminal stretchings (M-Od) were affected. Keywords: heteropolyanion; amino acid; vibrational spectra; Keggin 1. Introduction Heteropolyanions (HPAs) are widely used as solid and green catalysts for fine organic synthetic processes [1-8], corrosion resistant coatings, dopants in sol – gel matrices, membranes in selective electrodes, in gas detection apparatus, in solid-state electrochromic devices, etc [9-12]. However, although many HPAs have been shown to be biologically active, their biological properties have not been investigated much. To date two types of activity ? antiviral and, to a lesser extent, antitumoral ? have dominated their medicinal chemistry [13]. In the first area the effectiveness of these compounds against several viruses such as vesicular stomatitis, polio, rubella, rauscher leukemia, rabies, etc, has been studied [13]. The reasons for the biological activity of HPAs may include ionic size and charge, electron-transfer properties, the behavior of polyanions