转移印花增稠剂的流变性与微观形貌.pdfVIP

Vo l. 36 , No.9 纺织学报 第 36 卷第9 期 2015 年 9 月 Journal of Textile Research Sep. , 2015 DOI: 10. 13475/j. fzxb. 20140904607 转移印花增稠剂的流变性与微观形貌 李 青l ，苗赛男2 ，邢铁玲2 ，陈国强2 (1.武汉纺织大学化学与化工学院，湖北武汉 430200; 2. 苏州大学现代丝绸国家工程实验室，江苏苏州 215123) 摘 要 以转移印花纸涂层改性用增稠剂高取代泾丙基纤维素(H-HPC) 和竣甲基纤维素纳(CMC) 为研究对象，采 用稳态剪切和频率扫描相结合的方法研究了 H-HPC 、 CMC 溶液的流变性及其共混溶液在不同环境中的相容性，并 利用光学和原子力显微镜对 H-HPC 、 CMC 和糊料膜的微观形貌进行观测。结果表明 :CMC 的结构秸度高于 H-HPC 并体现出更明显的假塑性和触变性;随着 H-HPC 或 CMC 含量的增加，溶液的弹性增强且新性减弱;酸性、弱碱性以 及尿素对 H-HPC/CMC 溶液的表观花度和新弹性影响不大;在 80 c以上干燥时，可获得 H-HPC 和 CMC 共混均匀 且表面平整的糊料膜。 关键词 转移印花;增稠剂;流变性;微观形貌 中图分类号:TS 194.2 文献标志码 :A Rheology and morphology of thickeners in textile transfer printing 1 2 2 2 LI Qing , MIAO Sainan , XING Tieling , CHEN Guoqiang (1. College of Chem阳û Engineering , Wuhαn Textile Univers町， Wuhan , Hubei 430200 , China; 2. Nαtional Engineering Laborαtoryfor Modern Silk , Soochow University , Suzhou , Jiangsu 215123 , China) Abstract The high-s由stituted hydroxypropyl cellulose (H-HPC) and carboxymethyl cellulose (CMC) were used as the thickeners in the textile transfer printing. The rheologies of H-HPC , CMC and the compatibilities of H-HPC/CMC blend solution under the different conditions were investigated using the methods of steady-shear and frequency sweep. Meanwhile , the micro-morphologies of H-HPC , CMC and paste films were observed using optical and atomic force microscopes. The results show that CMC has a higher structural viscosity and exhibits more obvious pseudo-plastic characteristic an