1,4-二(4-羧基苯氧基)苯的制备及表征.pdfVIP

Vo l. 28 No.2 山东理工大学学报(自然科学版) 第 28 卷第 2 期 lournal of Shandong University of Technology(Natural Science Edition) Mar. 2014 2014 年 3 月 文章编号:1672-6197(2014)02-0014-04 1 ， 4-二(4-竣基苯氧基)苯的制备及表征 刘国红，宋明凤，金磊，李忠芳 (山东理工大学化学工程学院，山东淄博 25509 1) 摘 要:为了对 1 ， 4-二(4-援基苯氧基)苯进行研究，对氟苯甲腊和对苯二盼反应制备了1，4- 二(4- 腊基苯氧基)苯，井采用 1 ， 4- 二(4-睛基苯氧基)苯水解法制备了新型二酸单体 1 ， 4- 二 (4-援基苯氧 基)苯.通过考察反应温度、摩尔比对1，4- 二 (4-腊基苯氧基)苯以及 1 ， 4- 二 (4-援基苯氧基)苯产率 的影响，得到了最佳合成工艺条件.进行了熔点测定、红外以及核磁表征，结果表明合成的二腊为 1 ， 4-二(4-腊基苯氧基)苯，合成的二酸为 1 ， 4- 二(4-援基苯氧基)苯. 关键词: 1 ， 4-二(4-腊基苯氧基)苯; 1 ， 4- 二(4-援基苯氧基)苯;合成;表征 中固分类号: 069 文献标志码:A Preparation and characterization of 1,4-bis (4-carboxyl phenoxy) benzene LIU Guo-hong , SONG Ming-feng , JIN Lei , LI Zhong-fang (School of Chemical Engineering , Shangdong University of Technology , Zibo 255091 , China) Abstract: 1 , 4-bis (4-nitrile phenoxy) benzene is prepared by 4-fluorobenzonitrile and p-di- hydroxybenzene. 1 ,4-bis (4-carboxyl phenoxy) benzene is obtained by the hydrolysis of 1 ,4-bis (4-nitrile phenoxy) benzene. In order to get high productivity of 1 ,4-bis (4-nitrile phenoxy) ben- zene and 1 ,4-bis (4-carboxyl phenoxy) benzene , the effects of temperature and molar ratio are in- vestigated. The optimum conditions for synthetic process are attained. 1 ,4-bis (4-nitrile phenox- y) benzene and 1,4-bis (4-carboxyl phenoxy) benzene are characterized by melting point , IR and 1 H-NMR. Results indicate that 1,4-bis (4-nitrile phenoxy) benzene and 1 ,4-bis (4-carboxyl phe- noxy) benzene are synthesized successfully. Key words: 1 ,4-bis (4-nitrile phenoxy) benzene; 1 ,4-bis (4-carboxyl phen