从Cu2S到Cu（I）掺杂CdS纳米晶的可控离子交换法制备及光学、电学性能研究（英文）.pdf

SCIENCE CHINA Materials ARTICLES Published online 14 September 2015 | doi: 10.1007/s40843-015-0080-z Sci China Mater 2015, 58: 693–703 From Cu S nanocrystals to Cu doped CdS 2 nanocrystals through cation exchange: controlled synthesis, optical properties and their p-type conductivity research 1 1 2 3 4 1 1 Jian Liu , Yuheng Zhao , Jialong Liu , Shouguo Wang , Yan Cheng , Muwei Ji , Yuanmin Zhou , 1 2 1* Meng Xu , Weichang Hao and Jiatao Zhang Heterovalent doping represents an effective method to con- Along this direction, Cu(I) and Ag (I) ions could act as het- trol the optical and electronic properties of semiconductor erovalent dopants and control both optical and electronic nanocrystals (NCs), such as the luminescence and electronic impurities properties of II-VI NCs [6–11]. However, the impurities (p-, n-type doping). Considering the phase struc- common problem to be encountered in the case of Cu- ture diversity, coordination varieties of Cu atoms in Cu2S NCs, doped semiconductor NCs is the oxidation state of Cu ions and complexity of Cu doping in II-VI NCs, monodisperse Cu2S NCs with pure hexagonal phase were synthesized firstly. and induced stable p-type conductivity [12,13]. Evidence Then through cation exchange reaction between Cd ions and from several reports showe