壳聚糖修饰的金纳米复合粒子的制备与表征.pdfVIP

Vo l. 44 No.5 第 44 卷第 5 期 河南大学学报(自然科学版) 2014 年 9 月 Journal of Henan University (Natural Science) Sep. 2014 壳聚糖修饰的金纳米复合粒子的制备与表征 刘学军，程翠萍\李丹，李丽纳 (河南大学化学化工学院精细化工研究所，河南开封 475004) 摘 要:用半恍氨酸做稳定剂，壳聚糖做修饰剂，通过 NaB比还原 HAuCl，制备了稳定的金/壳聚糖复合纳米粒子 (Au/:S) ，并研究了反应物配比对金纳米粒子性能的影响.通过紫外-可见、红外、X 射线衍射及透射电镜对其结构 进行了表征.结果表明，当反应物选择合适的配比时可以合成性能良好的金纳米粒子. 关键词:金纳米复合粒子;半脱氨酸;壳聚糖F 制备;表征 中图分类号:0636.1 文献标志码:A 文章编号: 1003-4978(2014)05-0542--04 Preparation and Characterization of Gold Nanocomposite Particles Modified by Chitosan LIU Xuejun , ZHAI Cuiping 骨， LI Dan , LI Lina (lnstitute of Fine Chemical Engineering , College of Chemistry and Chemical Engineering , Henan University, Henan Kaifeng 475004 , China) Abstract: Au/CS nanocomposite particles have been synthesized by in-situ reduction of HAuCl , with NaBH , as a reductant in aqueous solution , using cysteine(Cys) as a stabilizer and chitosan(CS) as a modifie r. The effect of the ratio of reactants on the gold nanoparticles properties was also studied. The gold nanoparticles were characterized by UV-visible (UV-Vi时， fourier transform infrared spectroscopy (FT-IR) , X-Ray diffraction (XRD) and transmission electron microscopy (TEM). The results indicated that good performance of gold nanoparticles can be synthesized when choosing the appropriate ratio of reactants. Key words: gold nanocomposite particles; cysteine; chitosan; preparation; characterization 0 引言 近年来，金属纳米粒子已成为材料科学领域研究的热点.而金纳米粒子因其具有很好的化学稳定性和独 特的光学性质，在催化、生物传感、药