响应面优化法研究己二酸聚乙烯醇水凝胶的合成.pdfVIP

Vol. 44 No. 12 第44 卷第 12 期 应用化工 2015 年 12 月 Applied Chernical lndustry Dec.2015 晌应面优化法研究己二酸/聚乙烯醇水凝胶的合成 王永贵，刘芷晴，阙明君李永红，侯长平，王攀 (源州学院材料与化学工程学院，安徽 i除州 239∞0) 摘 要:聚乙烯醇具有良好的水溶性、胶膜性，但它的耐水性较差o 为了制备具有高强度耐水性的 PVA 水凝肢，以 己二酸为交联剂，对聚乙烯醇进行改性，用响应面法优化合成条件。结果表明，最佳反应条件为:PVA 的质量浓度 8% ，反应温度 88.5 C，反应时间1. 6 h ， PVA 与己二酸质量比8.21: 1 。红外光谱、X 射线衍射分析表明，PVA 与己 二酸之间形成了交联结构，改性后的 PVA 水凝股具有较高的耐水性，可达86.3% 。实践证明采用响应面法对实验 的合成工艺进行优化是非常有效的。 关键词:交联剂;聚乙烯醇;响应面优化法:胶甜剂;耐水性能 中固分类号:TQ633.1;0631. 5 文献标识码:A 文章编号:1671 -3206(2015)12 -2264-04 Optimization of synthesis of adipic acid-PVA hydrogel adhesive by response surface methodology WANG Yong-gui ,LIU Zhi-qing ， κ4N Ming-jun ,LI Yong-hong ,HOU Chαng-pmg ， 职4NGPα， n ( Sch∞1 of Materials and Chernical Engineering of Chuzhou Univers坷，Ch皿hou 239仪泊，China) Abstract: Polyvinyl alcohol (PVA) adhesive has good water solubility and good film properties ,but its water-soluble limits the application. Preparation of high strength and water resistance of PVA hydrogel ad- hesive with 由e modification of polyvinyl alcohol (PVA) adhesive using adipic acid as cross-linking a- gent. Response surface methodology (RSM) was utilized for optimization the reactive conditions. The re- sult showed 由at the optimum reaction condition were as folIows: the mass concentration of PVA adhesive was 8% ,the reaction temperature was 88. 5 c .由e reaction time was 1. 6 h and the mass ratio of PVA to adipic acid was 8.21: 1. FTIR and XRD show that a cross-linked structure was formed between PVA and adipic acid ,which led the adhesive having high water resistance.