无皂乳液聚合的进展 - 林中祥胶粘剂技术信息网.PDF

20032 　　 　　　　　　　 20　 1 Feb.2003 CHEMICAL　INDUSTRY　AND　ENGINEERING Vol.20　　No.1 1 2 1 1 1 王玉霞, 张　芳, 王艳君, 袁才登, 曹同玉 (1., 300072;2., 300131) :本文介绍了无皂乳液聚合的反应机理(包括成核机理和核增长机理)、反应动力 学, 着重介绍了影响无皂乳液稳 性的因素以及提高无皂胶乳稳 性和固含量的方 法, 包括引发剂碎片法、引入亲水性或表面活性单体法、调整聚合反应的分散介质法 和选择适当的聚合工艺法。并概括了当今无皂乳液聚合的研究动态、应用和发展前 景。 :无皂乳液聚合;乳液稳 性;固含量;前景 + :TQ316.33 4　:A　:1004-9533(2003)01-0015-05 Development in Emulsifier-Free Emulsion Polymerization WANG Yu-xia, ZHANG Fang,WANG Yan-jun, YUANG Cai-deng, CA Tong-yu (1.School of Chemical Engineering,Tianjin University, Tianjin 300072, China; 2.School of Tianjin First Light Industry, Tianjin 300131, China) Abstract :In this paper, the mechanism(including the nucleation and growth of polymer parti- cles)and kinetics of emulsifier-free emulsion polymerization was presented.The factors to in- fluence the stability and the ways to improve the stability and solid content of emulsifier-free polymer emulsion were reviewed in detail.The ways include the introduction of initiator frag- mentation, hydrophilicor surfactant comonomers, modification of reaction medium and selection of proper prosesses.Also the present status of application and foreground in the research field was outlined. Key words:emulsifier-free emulsion polymerization;stability of emulsion;solid content;pros- pect :2002-05-22 :(1978-), , , , 。 　　1　6 　 　　　　　　 2003 2 　　 , [14] 。 。Chang St , , ,