负载型催化剂的催化性能及其结构关系.pdfVIP

第39卷 第l2期 哈 尔 滨 工 业 大 学 学 报 Vo1．39 NO．12 2 0 0 7年 l2月 JOURNAL OF HARBIN INSTITUTE OF TECHNOLOGY Dec．2007 负载型催化剂的催化性能及其结构关系 李 娜，尤 宏，姚 杰，黄君礼 (哈尔滨工业大学市政环境工程学院，哈尔滨150090，E—mail：yokelist@vip．sina．c0m) 摘 要：以 一A1：O，、SiO：为载体，V：O 和TiO：作为活性成分，制备出负载型催化剂．以甲苯的催化氧化作 为模型反应，对所制得的催化剂进行活性实验．结果表明，V O 一TiO ／SiO：对甲苯的去除效果最好，起燃温 度低，与贵金属催化剂具有相似的活性和温度特性，具有较强的抗冲击能力．该催化剂的V O 最佳负载量 为l％，／Tb(V)：／Tb( )为0．127．活性测试和XRD、XPS表征结果表明：较少的V 0 负载量使得V元素嵌入 了TiO：的晶体结构中，而不是形成结晶的V：O ，并形成了V—O—Ti键；TiO：与SiO：发生了化学反应有Ti — O—Si键形成．这些化学键有可能是催化剂的活性位，它们的生成有利于提高催化剂的催化性能，有利于 增加催化剂各组分间的结合力． 关键词：催化氧化；V O5一TiO ；SiO2；A12O3；催化剂结构 中图分类号：X703．5 文献标识码：A 文章编号：0367—6234(2o07)12—1873—05 Relationship between catalytic performance and structure of supported catalyst U Na，YOU Hong，YAO Jie，HUANG Jun—li (School of Mtmicipal and Environmental嘲 f艘 『lg，Harbin Institute of Technology，Harbin 15(3090，China，E—mail：yokelist@rip．sina．COrn) Abstract：The supported catalysts which can effectively remove organic compounds discharged to atmosphere were prepared，using^y—M2 O3 or SiO2 as carriers，V2 O5 or TiO2 as active components．The catalytic oxidation of methylbenzene was used as model reaction，and the activity of prepared catalysts was investigated．The exper— imental results indicated that V2 O5一TiO2／SiO2 showed the best catalytic activity for the degradation of methyl· benzene，with low initial temperature．V2 O5一TiO2／SiO2 gave similar activity and temperature characteristic compared with noble metal and possessed better resistance against impact．The optimum loading amount of V2 O5 was 1％，the rate ofm(V)：m(Ti)was 0．127．And the prepared catalysts were characterized on the structure and morphology by XRD and XPS．According to the activity test and characterization，the relationship between the structure of catalysts