GCMS法测定水基胶中苯及苯系物的不确定度.pdfVIP

烟草科技I Tobacco Science Technology 烟草化学厅。bacco Che皿s町 2014 年第 7 期(总第 324 期) GC/MS 法测定水基胶中苯及苯系物的不确定度 撮志鹏，吕长平，王文婷，彭 氓，杨字铭 甘肃烟草工业有限责任公司技术研发中心，兰州市南滨河中路1111 号 730050 摘要:为了提高气相色谱-质谱联用法测定水基肢中苯及5 种苯系物(甲苯、乙苯、对二甲苯、间二甲苯、 邻二甲苯)结果的准确性，通过数学模型的合理构建，分析了该方法测量不确定度的主要来源，计算得到 6 种测定物的扩展不确定度值介于0.006-0.019 mg/kg 之间 (k=2 ) 。根据各不确定度分量所占的权重大小， 分析得出 5 种实验选定的因素对于测定结果影响程度依次为:环境温度〉样品的多次测量〉静直时间〉器 具称量〉曲线拟合。 关键词:气相色谱-质谱联用法;水基胶;苯系物;不确定度 中固分类号: TS426 文献标识码:A 文章编号: 1002-0861(2014)07-0045-06 Evaluation of Uncertainty in Determination of Benzene and its Homologues in Water - based Adhesive by GC/MS ZANG Zhipeng , LÜ Zhangping , WANG Wenting , PENG Sa , and YANG Yuming Technology RD Center , Gansu Tobacco Industrial Co. , Ltd. , Lanzhou 730050 , China Abstract: In order to improve the accuracy of test results , the measurement uncertainty of benzene and its five homologues (toluene , ethylbenzene , p-xylene , m-xylene , o-xylene) in water-based adhesive by GC/MS was analyzed and evaluated via establishing rational mathematical models and analyzing the main sources of uncertainty in this measuring method. The results showed that the expanded uncertainty values of the six analytes ranged from 0.006 to 0.019 mg/kg (k=2). On the basis of the weights of various components of uncertainty , the five selected experimental factors in the order of their influence on determination results were ambient temperature repeated measure standing time apparatus measuring curve fitting. Keywords: GC/MS; Water-based adhesive; Benzene homologue; Uncertainty 的致癌作用[日]。因此，提高水基胶中苯及苯系物测定 烟用水基胶是卷烟生产中必不可少的卷接材料，为 的能力水平对于烟用材料的安全控制具有重要意义。 了满足工艺上的特殊要求，水基胶通常是由几种主料 近年来，化学工作者将不确定度评定作为衡量检测结 复配而成，因此成分比较复杂，这也给产品的安全控制 果可靠性及可信赖程度的重要指标[67] ，并且进行了大 带来了更多的困难ilJ