HJ 636—2012测定总氮时影响空白值因素分析.pdfVIP

环境工程 126 Environmental Engineering HJ 636-2012 测定总氮时影响空白值因素分析* 潘忠成李敏 (北京林业大学环境科学与工程学院水体污染源控制技术北京市重点实验室，北京 100083) 摘要:碱性过硫酸饵氧化紫外分光光度法(HJ 636-2012) 测定水中总氮时，经常出现空白值偏高的现象。为此，从总 氮的测定过程出发，探讨了影响总氮测定的因素。结果表明:过硫酸御的纯度对空白值的影响最大;氢氧化纳的纯度 对空白值也有一定的影响;实验中可用去离子水代替无氨水;当室温超过 27 t:时，碱性过硫酸饵溶液的存放时间最好 不超过 3 d; 不同的消解设备对空白值的影响不明显。 关键词:总氮测定;空白值;标准;碱性过硫酸饵 DOI: 10. 13205/j. hjgc. 201601028 ANALYSIS OF INFLUENCING FACTORS ON THE BLANK VALUE OF TOTAL NITROGEN DETERMINA TION BY HJ 636-2012 PAN Zhong-cheng , LI Min (College of Environmental Science Engineeri吨， Beijing Key Lab for Source Control Technology of Water Pollution , Beijing Forestry University , Beijing 100083 ,China) Abstract: The phenomenon of high blank value of total nitrogen in water was determined by Alkaline potassium persulfate oxidation UV spectrophotometry method (HJ 636-2012). Therefore , the paper discussed the influencing factors of total nitrogen determination according to the process of dete口nination of total nitrogen. The results showed that the purity of potassium sulfate was the greatest impact on blank value. The purity of sodium hydroxide had a certain effect on the blank value. In the experiment , we could use the deionized water to replace non-ammonia wate r. When the room temperature exceeded 27 t: , the storage time of alkaline potassium potassium sulfate solution was preferably no more than three days. The different digestion equipment had no obvious impact on blank value. Keywords: total nitrogen determination; blank value; standard; alkaline potassium persulfate o sl 言