X射线荧光光谱法测定石膏中11种元素的含量.pdfVIP

PTCA(PART B: CHEM. ANAL.) 司E主ZE X 射线荧光光谱法测定石膏中 11 种元素的含量 韩蔚，丁建军，梅一飞，马振珠 (中国建材检验认证集团股份有限公司，北京 100024) 摘要:采用 X 射线荧光光谱法测定石膏中纳、娱、铝、硅、硫、钟、钙、铁、住、铁、银、等 11 种元素 的含量。样品研磨 30 s 后压片，样片用于 X 射线荧光光谱分析。以 GBW 03109 、 GBW 03110、 GBW 03111 、 GBW 03109a、 GBW 03111a、 GSB 08 一1352-2001 、 GSB 08-1352-2006、 GSB 08 • 1352一2009 等 8 种标准物质为基础制作校准曲线，优化了各元素的基体校正数学模型。各元素的 检出限在 O. 001 4%~0. 27%之间。对同一石膏样品平行测定 10 次，其相对标准偏差Cn= 10) 在 O. 51%~4. 0%之间。方法用于 3 个石膏样品的分析，所得结果与国家标准方法测定结果相符。 关键词:X 射线荧光光谱法:石膏2 元素 中图分类号: 0657.34 文献标志码:A 文章编号: 1001-4020(2015)02-0188-04 XRFS Detennination of 11 Elements in Gypsum HAN Wei , DING Jian-jun ，即IEI Yi-fei , MA Zhen-zhu CChina Building Material Test and Certification Group Co. , Ltd. , Beijing 100024 , China) Abstract: XRFS was applied to dete口nine the concentration of 11 elements , i. e. Na , Mg , Al , Si , S , K , Ca , Ti , Mn , Fe and Sr in gypsum. The sample was grinded for 30 s and squashed into disc shaped to be used for XRFS analysis. Calibration curve was prepared with 8 CRMs of GBW 03109 , GBW 03110 , GBW 03111 , GBW 03109a , GBW 03111a , GSB 08-1352-200 1, GSB 08-1352-2006 and GSB 08-1352-2009. The mathematical models of matrix correction of the 11 elements were optirnized. Detection lirnits of the 11 elements were found in the range of 0.0014%一0.27%. Values of RSDs Cn=10) were found to be in the range of O. 51%-4. 0% by analysis of a sample of gypsu皿 The proposed method was used in analyzing 3 samples of gypsum , giving results in consistency with those obtained by the GB method. Keywords: XRFS; Gypsum; Element 随着人们对环境安全认识的逐步加深，对绿色