载氧化锡碳基纤维的制备表征及催化裂解制备生物液体燃料.pdfVIP

62 CHINA 0IL5 AND FA四 2016 VoL 41 No. 11 载氧化锡碳基纤维的制备表征及催化裂解 制备生物液体燃料 黎忠根1 ，李昌珠2 ，肖志红2 ，刘汝宽2 ，黄志辉1 (1.中南大学机电工程学院，长沙 41∞83; 2. 湖南省林业科学院，长沙 41仪泊的 摘要:以铁盐和葡萄糖为原料，采用溶肢-凝肢法和般烧工艺制备了破基(Fe/C) 纤维，通过 X- 射线 衍射(XRD) 和扫描电子显微镜(5EM) 对其结构形貌进行了表征。以所制备的 Fe/C 纤维为载体，通 过浸渍法得到载氧化锡破基(5n0 - Fe/C) 纤维，通过SEM 对其结构形貌进行了表征。以 Sn0 - Fe/C 2 2 纤维为催化剂，进行大豆油催化裂解试验，考察了催化剂用量、裂解时间及裂解温度对产物收率的影 响。结果表明:当催化剂用量1.4% 、裂解时间 2h、裂解温度桐o t:时，液相产物收率在 80% 以上。 关键词:溶肢-凝肢法;载氧化锡破基纤维;催化裂解;生物液体燃料 中圈分类号:T币45; 四.63 文献标识码:A 文章编号:1∞3 -7969(2016)11-∞62 -04 Preparation and characterization of Tin dioxide carbon fiber and i臼 catalytic cracking for preparation of biological liquid fuel LI Sigen , LI Changzhu2 , XIAO Zhihong2 , LIU Rukuan2 , HUANG Zhihui 1 (1. College of Mechanical and Electrical Engineeri鸣，Central South University ,Changsha 410083 , China i 2. Hunan Acaderny of Fores町，Changsha 41叹泊4 ， China) Abstract: With ferric nitrate and glucose 臼 raw rnaterials , carbon (Fe/C) fiber was prepared by sol - gel method and calcination process ,and characterized by X - ray diffraction (XRD) and scanning electron microscope( SEM). With (Fe/C) fiber 嗣 carrier ， Tin dioxide carbon fiber( 5n02 - Fe/C) w描 obtained by irnpregnation rnethod ,and characterized by SEM. With 5n02 - Fe/C as catalyst ,catalytic cracking ex- periment of soyhean oil was carried out. 咀le impacts of catalyst dosage ,cracking time and cracking temper- ature on the product yield were investigated. The results showed 出at under the conditions of catalyst dosage 1. 4 % ,cracking tirne 2 h and cracking ternperature