便携式气相色谱质谱测定水中挥发性有机物再现性和准确度研究.pdfVIP

第 29 卷第6 期 Vo l. 29 No.6 中国环境监测 2013 年 12 月 Environmental Monitoring in China Dec. 2013 便携式气相色谱质谱测定水中挥发性有机物再现性和准确 度研究 封跃鹏，房丽萍，邱赫男，王伟 环境保护部标准样品研究所，北京 100029 摘 要:建立了便携式顶空-气相色谱-质谱( HS-GC-MS) 测定水中挥发性有机物的方法。以水中苯系物、卤代烧和氯代 苯等 VOCs 为研究对象，在同一实验室内，使用 3 台便携式 HS-GC-MS 模拟现场应急监测环境开展检测活动，研究测定结 果的再现性和准确度。实验结果表明，检测结果的相对标准偏差为 0.7% -13%; 绝大多数目标化合物测定结果的回收 率为 80% -120% 。综合来看，方法的精密度和准确度基本满意，能够满足应急监测工作的需妥。 关键词:便携式 GC-MS; 准确度;再现性;应急监测;挥发性有机物 中图分类号:X830.2 文献标志码:A 文章编号: 1002.{i002 ( 20 日)06-0117 -06 Study 00 Reproducibility aod Accuracy of Determioiog Volatile Orgaoic Compouods io Water by Portable GC.MS FENG Yue-peng.FANG Li-ping.QIU He-nan.WANG Wei Institute for Reference Materials of Ministry of Environmental Protection. Beijing 100029. China Abstract: A method for portable gas chromatography and mass spectrometry (GC-MS) was established to analyze volatile organic compounds (V OCs) in water. At a same laboratory. the benzene and its analogies ( BTEX) 、 halo-hydrocarbons and chlorobenzenes of VOCs in water were determined by portable headspace (HS) -GC-MS in order to study their analytic reproducibility and accuracy. The result reaches reproducibility with the RSD from 0.7% to 13% •as well as accuracy with the recoveries for most compounds from 80)串 to 120%. Generally. the precision and accuracy of the method were satisfied to meet the demand of emergency momtonng. Key words: portable GC-MS; accuracy; reproducibility; emergency monitoring; volatile organic compounds VOCs 为研究对象，在同一实验室内，将 6 名分 近年来，由于经济的快速增长和对安全生 析人员分成3 组，模拟现场应急监测工作环境， 产、运输等的不太重视，导致影响环境质量的突 使用 3 台便携式 HS-GC-MS 开展检测活动，研究 发事故频发，促使中国许多环境监测部门建立