冷原子蒸气发生-原子荧光光谱法测定尿中汞.pdfVIP

PTCA(PART B: CHEM. ANAL.) ~盈E 四)1:10. 11973/ltûy-hx201507015 |tr.，.:I:. l乍商报 冷原子蒸气发生-原子荧光光谱法测定尿中东 杨雪姬，黄灿东 (广州市第十二人民医院，广州 510620) 摘要:采用冷原子蒸气发生-原子荧光光谱法测定尿中的朵。尿样加入涣化剂处理后，直接用 冷原子蒸气发生原子荧光光谱法测定呆的含量。呆的质量浓度在 O. 15~10. 0μg. L-] 范围内呈 线性，检出限(35) 为 0.15μg. L-] 。方法用于质控样品的分析，测定值与认定值相符，测定值的相 对标准偏差Cn=6)在 2. 8%~3. 8%之间。应用此方法对实样进行测定，结果与冷原子吸收光谱法 的测定结果相符。 关键词:原子荧光光谱法;冷原子蒸气发生;尿中呆 中图分类号: 0657.31 文献标志码:A 文章编号: 1001-4020(2015)07-0955-04 CV-AFS Determination of Mercury in Urine YANG Xue-ji , HUANG Can-dong (The 12th Guangzhou Municiμ1 Peoρles Hosρital ， Guangzhou 510620 , China) Abstract: CV-AFS was applied to the determination of mercury in urine. The sample was treated with bromination agent , and the content of mercury was determined directly by CV-AFS. Linearity range of mercury was found between O. 15 一 10.0μg • L-1 , with detection limit (3s) of O. 15μg L• 1 In analysis of quality control materials by this method , the results obtained were in consistency with the certified values , with RSD s (n二6) in the range of 2. 8%-3. 8%. The proposed method was applied to the analysis of substantial urine samples , giving results in agreement with those obtained by CV-AAS. Keywords: AFS; Cold atomic vapor generation; Urine mercury 测定尿中求含量的常用方法有双硫踪分光光度 在工业上接触隶的机会较多，如仪器仪表的制 法、氯化亚锡还原-冷原子吸收光谱法和原子荧光光 造与维修、塑料工业、染料工业、隶齐法提取金、银等 谱法[2J 等。原子荧光光谱法是我国近年来发展较快 贵金属等;在生活中也有很多接触机会，如接触或服