废轮胎热解炭黑的表面修饰及其在平版印刷油墨中的应用.pdfVIP

Chinese J. Chem. Eng叫 14(5) 654• 659 (2006) Surface Modification of Pyrolytic Carbon Black from Waste Tires and Its Use as Pigment for OfTset Printing Ink* ZHOU Jie(周沽)a，b， WANG Jingdai(王靖岱)飞 R配N Xiaohong(í:f晓红t， YANG Yongron邵阳永 荣t and JIANG Binbo(蒋斌波t树 a UNILAB Research Center for Chemical Reaction Engineering , Department of Chemical Engineering, Zhejiang .university, Ha吨zhou 310027 , China u Department of Environmental Scíence and Engíneering, Hangzhou Dianzi Uníversity, Hangzhou 310018 , China Abstract Pyrolysis has the potential of transforming waste into valuable products. Pyrolytic carbon black (PCB) ís one of the most important products resulting from the pyrolysis of used tires. One of the most significant applica偏 tions of modified pyrolytic carbon black is its use as pigment for offset printing ink to obtain high added values. Inverse gas chromatography (IGC) results show that a large quantity of inorganic matters and carbonaceous deposit are removed by treating the pyrolytic carbon black with nitric acid solution. Plenty of active sites originally occu- pied by inorganíc ash and c伽are recove时Thesu巾ceen叩向yrolytic carbon bl础 (TWPC) modified by titanate-coupling 咿nt-叩cially the spωific interaction Y:P determined by the specific.probe molecule，时1- ene-shows the strong interaction between the TWPC and the synthetic resins. Th巳 offset printing ink performance confirms the IGC prediction. And TWPC has the great potential of applications in printing ink industry as pigment. Keywords environmental engineering, waste tires , ink 1 INTRODUCTION tant materials of publishing industry. The need of the Waste tires do not degrade in a short span of time; dom巳stic offset printing