吸附相反应技术制备沸石负载TiO2光催化剂.pdfVIP

第28卷第6期 青岛科技 大学学报(自然科学版) Vo1．28 No．6 2007年 12月 Journal of Qingdao University of Science and Technology(Natural Science Edition) Dec．2007 文章编号：1672—6987(2007)06—0486—04 吸附相反应技术制备沸石负载TiO2光催化剂 孙举涛 (青岛科技大学 橡塑材料与工程教育部重点实验室，山东青岛266042) 摘 要：以钛酸丁酯为钛源，天然沸石为栽体，采用吸附相反应技术，以沸石表面吸附的水 层为“纳米反应器”，制备了沸石／TiO 光催化剂。运用红外光谱分析和X一射线光电子能 谱分析对沸石／TiOz光催化刺进行了表征。结果表明，在沸石表面成功地负载了纳米 TiO 。以250W紫外线高压汞灯为光源，以有机颜料甲基橙为目标降解物，研究了沸石／ TiO 光催化剂的光催化性能，并探讨了沸石中TiO 负载量、沸石／TiO 用量与催化剂催 化活性之间的关系。结果表明，当沸石与钛酸丁酯质量比为1：3时，沸石／TiO2光催化 荆具有较好的光催化活性。提高沸石／TiO 光催化剂的用量能提高其对甲基橙溶液的光 催化降解效率。 关键词：吸附层；纳米反应器；沸石；TiO2；光催化剂 中图分类号：O 641 文献标识码：A Preparation of TiO5 Loaded Zeolite Ph0t0catalysts by Adsorption Phase Nanoreactor Technique SUN Ju-tao (Key Laboratory of Rubberplastics，Ministry of Education， Qingdao University of Science and Technology Qingdao 266042，China) Abstract：The titanium dioxide(TiO2)based photocatalysts were prepared on the ad— sorption layer of the zeolite which acted as a“nanreactor”．The zeolite／TiO2 photocata- lysts were characterized by IR and X—Ray photoelectron energy spectrum analysis．The results indicated that nanometer TiO2 was successfully prepared on the surface of zeolite． The photocatalytic properties of zeolite／TiOz photocatalysts were studied by degradation of methyl orange under a 250 W ultraviolet light irradiation．And the effects of TiO2 a— mount and zeolite／TiO2 photocatalyst amount on photocatalytic activity were examined． The results showed that the photocatalyst was of better photocatalytic activity when the rate of TiO2 to zeolite is 1：3．Furthermore，the photocatalytic efficiency was improved wh