工作场所空气中HF、HCl、H2SO4离子色谱法测定的研究.pdfVIP

中国卫生检验杂志2007年l2月第l7卷第l2期 Chinese Journal of Health Laboratory Technology，Dec 2007；Vol 17 No 12 2197 【化学测定方法】 工作场所空气中HF、HCl、H2 SO4离子色谱法测定的研究 黄碧兰，张英，黄珠晏 (广东省深圳市龙岗区疾病预防控制中心，广东深圳 518172) [摘要] 目的：探讨一次采样用离子色谱法同时测定工作场所空气中有毒物质HF、HC1、H：SO 的含量。方法：以多孔玻 板吸收管采样，离子色谱法测定。结果：方法采样效率92％，方法的检测限HF 0．02 mg／L，HC1 0．12 mg／L，H SO 0．14 mg／L，精密度试验均小于10％。回收率92．6％一105．8％。结论：本法灵敏度高，选择性好，操作简单。方法的线性 范围、检出限、采样效率、准确度和精密度均符合方法学要求，且一次采样可同时分析工作场所空气中HF、HC1、H SO 浓 度，此法适用于职业卫生日常监测要求。 [关键词] 离子色谱法；氟化氢；氯化氢；硫酸 [中图分类号] 0657．7’5 [文献标识码] A [文章编号] 1004—8685(2007)12—2197—02 Determination of HF，HCI and H2 SO4 in workplace air using IC Huang Bi—lan，Zhang ，Huang Zhu一 (Longgang Center for Disease Control and Prevention，Shenzhen 518172，China) [Abstract] Objective：To develop a method for determination of HF，HC1 and H2SO4 in workplace air．Methods：Samples were detected by ion chromatography(IC)after being collected t}l multi—hole absorbing tubes．Results：The efficiency of sample collecting was high(92％)．The detection limit of HF was 0．02 mg／L，HC1 was 0．12 mg／L，H2SO4 was 0．14 mg／L The RSD was less than 10％．The rate of recovery Was 92．6％ ～105．8％．Conciusion：The method is sensitive．selective and simple for the determ ination of HF，HC1 and H2 SO4 in workplace air．The linear range of detection limit，efficiency，accuracy and precision re— quirements are in line with methodology．The law applies to monitoring day—to—day requirement of the occupational health． [Key words] Ion chromatography(IC)；HF；HC1；}{2SO4 深圳市龙岗区工厂众多，许多作业环节要用到氟化氢、氯 1．3 采样 化氢、硫酸。而这几种都是有毒有害的物质，会危害人体健 在采样点，用一只装有 10．0 ml淋洗液作为吸收液的多孔 康。因此测定空气中氟化氢、氯化氢、硫酸的含量，了解作业 玻板吸收管，以1 L／min流量采集15 min空气样品。采样后， 场所中空气的污染状况，对保护作业工人的身体健康有非常 立