种貉被毛微量元素的分析.pdfVIP

四川动物2008年第27卷第4期 Sichuan Journal of Zoology Vo1．27 No．4 2008 种貉被毛微量元素的分析 侯天平 ，王松君 ，常平 ，侯悦 (1．吉林工程技术师范学院，长春130052；2．苏州科技学院化学与生物工程学院； 3．吉林大学地球勘探与科学学院；4．浙江大学材料化工学院) 摘要：采用低温干灰化法制备样品，ICP—AES同时分析毛皮动物貉被毛组织中多种微量元素。Ba、Be、cd、si、Y 和zn的测定下限为1．0～9．0 ng·g-1级，B、Fe、La、Mg、Mo、 、 、Co、cr、Cu、Sr、V和Zr为0．O1～0．09 g·g 级， In、Th、P和为0．13～0．23 g·g 级，大于1的只有 Nb是 1．08 g·g 级。该方法经国家人发标准物质 GBW07601验证，测得方法相对误差在0．83％～9．59％之间，相对标准偏差在0．81％～5．20％之间，各项检测指标 均能满足生物样品检测要求，分别测得健康种貉、自咬症轻重病貉被毛中的22种微量元素，健康貉的B、Co、Cr和Ni 微量元素含量明显高于病貉，而Al、Ba、Be、Cd、Mo、Pb、Sr、Ti和Zr元素含量较低。该方法可以满足生物样品元素分 析的要求。 关键词：貉；被毛组织；分析；微量元素 中图分类号：$865；Q959．8 文献标识码：A 文章编号：1000—7083(2008)04—0642—03 Analysis of Trace Elelments on Raccoon Dog Fur HOU Tian．ping ，WANG Song-jun ，CHANG Ping。，HOU Yue (1．Jilin Teachers Institute of Engineering and Technology，Changchun 130052，China；2．Suzhou University of Science and Technology of Chemistry and Bioengineering；3．College of Geoexploration Science and Technology，Jilin University； 4．College of Material and Chemical Engineering，Zhejiang University) Abstract：The sample was prepared by low temperature dry ashing method．Trace elements of fur tissue on fur—bearing an— imal raccoon dog were analyzed by inductively coupled plasma—atomic emission spectrometry(ICP—AES)．The lowest quanti— tatively determinable concentration were between 1．0～9 0 ng·g grade for trace elements Ba，Be，Cd，Si，Y and Zn， and were between 0．Ol～0．09 p．g·g～grade for microelement B，Fe，La，Mg，Mo， ，Ti，Co，cr，Cu，Sr，V and Zr， and were between 0．13～0．23 g‘g～grade for In，Th，P and Pb．Only one ofgreater than 1 on the lowest quantitatively determinable concentration for Nb was 1．08 ·g。。．This method