第一节催化剂在化学反应中的作用-IIS7.ppt

Chapter 5 Techniques in Green Chemistry Chapter 5 Techniques in Green Chemistry 5.1 The performance of Catalysts in Chemical reaction 5.2 Green Chemistry and Catalysis 5.3 The Design of High Efficient and Safe Catalyst 5.4 Changing Starting Material for Chemical reaction 5.5 Changing Reagents 5.6 Changing the solvent of Chemical Reaction 5.7 Process Control and Process Intensification References 5.1 The performance of Catalysts in Chemical reaction Accelerate the chemical reaction rate. Accelerate selectively one of the several thermodynamically possible reactions and yield selectively the special products. Namely, the use of catalysts can control the selectivity for special products. Control the enantioselectivity of reaction. Catalyst has been called as molecular machine Synthesize the special conformation of chiral isomers: The consideration of incorporating the catalyst with the reaction conditions could control the selectivity of chemical reaction. Catalyst has been called as molecular machine Catalyst has been called as molecular machine Hence, those enzyme have been called as Molecular Machine. Recent investigations have reported that not only enzyme acts as molecular machine but also the common catalysts own the similar functions. The classical example is the metal cyclopentadiene (环戊二烯) complex which was used as the catalyst in olefin polymerization. Catalyst has been called as molecular machine Enzyme and other traditional chemical catalyst, If they exhibit high specificity, selectivity, yield and atom economy, they should be considered as the molecular machine with special functions in chemical reactions. Catalyst has been called as molecular machine Chapter 5 Techniques in Green Chemistry 5.1 The performance of Catalysts in Chemical reaction 5.2 Green Chemistry and Catalysis 5.3 The Design of High Efficient and Safe Catalyst 5.4 Changing Starting Material for Chemical reaction 5.5 Changing Reagents 5.6 C