酚醛树脂（Phenolic resin）.doc

酚醛树脂（Phenolic resin） 1. Preface: Phenolic resin is one of the worlds first discovered and industrialize thermosetting resins, as reactants, synthesis process is convenient, and has good mechanical strength and heat resistance, excellent mechanical properties and electrical properties, high temperature creep resistant to heat, fire, etc, to now is still widely used in mould plastics, coatings, friction materials, adhesives, casting resin, plastic foam, etc. But with the rapid development of industrial economy, the performance of phenolic materials has been increasingly demanding. The reaction mechanism, structure and properties of phenolic resin are still studied in deep human studies. The toughening of phenolic resin, fiber enhancement, nano and other modification have achieved many results. Many new varieties of phenolic composite materials are also listed in the engineering plastic series. Phenolic hydroxyl and methylene in phenolic resin were easily oxidized, which affected its heat resistance, and the phenolic resin was brittle after curing. Therefore, it is still an important task to improve the phenolic resin and apply the results to industry. 2. Technical development status: The development of phenolic molding compound, its in the final analysis to studies of phenolic resin modified, now the modification of phenolic resin which mainly in the following aspects: 1. The use of natural vegetable oil modified phenolic resin; 2. Modified phenolic resin by thermoplastic resin; 3. Low molecular chemical modified phenolic resin; 4. Thermosetting resin modified phenolic resin; 5. Rubber modified phenolic resin; 6. Nanomaterials toughened phenolic resin; 7. Thermotropic liquid crystal toughening phenolic resin. 2.1 natural vegetable oil modified phenolic resin Natural vegetable oil modified phenolic resin belongs to the chemical modification, molecular structure of vegetable oils contain a double bond or conjugate three key flexible chain, through the double bond or par