酸性离子液中纤维素的水解-催化学报.PDF

第 30 卷 第 4 期 催 化 学 报 2009 年 4 月 Vol. 30 No. 4 Chinese Journal of Catalysis April 2009 文章编号: 0253-9837(2009)04-0279-05 研究论文: 279~283 酸性离子液中纤维素的水解 姜 锋, 马 丁, 包信和 中国科学院大连化学物理研究所催化基础国家重点实验室, 辽宁大连 116023 摘要：以离子液 1-丁基-3- 甲基咪唑氯为纤维素溶剂, 酸性离子液 1-磺酸丁基-3- 甲基咪唑氯为催化剂进行了纤维素水解反应. 通 过筛选, 找到了合适的离子液共溶剂二甲基甲酰胺可降低纤维素-离子液体系的黏度. 分别考察了催化剂用量和水含量对纤维 素水解的影响, 同时研究了高聚合度的滤纸及棉花的水解行为. 应用二硝基水杨酸法测得水解体系中还原糖的浓度, 进而求得 反应过程中还原糖的收率. 结果表明, 在酸性离子液中水解纤维素是完全可行的, 最高可达到 95% 的还原糖收率. 关键词：纤维素; 水解; 离子液; 酸性离子液; 总还原糖 中图分类号：O643 文献标识码：A Acid Ionic Liquid Catalyzed Hydrolysis of Cellulose * JIANG Feng, MA Ding , BAO Xinhe State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinses Academy of Sciences, Dalian 116023, Liaoning, China Abstract: The hydrolysis of cellulose in acid ionic liquids was investigated systematically. Ionic liquid 1-butyl-3-methylimidazolium chlo- ride was used as the solvent of cellulose, and acid ionic liquid 1-butyl sulfonic acid-3-methylimidazolium chloride was used as the catalyst. A proper co-solvent dimethylformamide was selected to reduce the viscosity of the cellulose-ionic liquid system. The effects of acid ionic liq- uid content and water content in the system were also investigated. Filter paper and cotton were used as substrates for the hydrolysis reaction. The dinitrosalicylic acid (DNS) method was employed to monitor the whole hydrolysis process. It was proved that this novel hydrolysis process is totally feasible, and the total reducing sugar yield is up to 95%. Key words: cellulose; hydrolysis; ionic liquid; acid ionic liquid; total reducing sugar