包裹法制备MoSi2／Cu基合金复合粉体的影响.pdfVIP

下半月出版 MaterialHeat Treatment]材料热处理技术 包裹法制备MoSi2／Cu基合金复合粉体的影响 郭铁明 。陈 辉 。马 勤I． 。邹欣伟·。赵红顺· (1．兰州理工大学 甘肃省有色金属新材料省部共建国家重点实验室，甘肃 兰州 730050；2．兰州理工大学 有色 金属合金省部共建教育部重点实验室．甘肃 兰州 730050) 摘 要：采用非均相成核法制备了二硅化钼弥散强化铜的复合粉体，利用激光粒度分析仪、扫描电镜、X射线 衍射仪等分析手段对复合粉体进行表征，并讨论了包覆结构的形成机制和影响因素。结果表明：MoSi：颗粒表面 被细小的铜微晶包裹，MoSi：颗粒的分散性得到显著改善；MoSi：颗粒大小和形状对复合粉体的包裹有较大影响； 酸性溶液可有效防止复合粉体的团聚，包裹效果较好。包覆结构取决于铜在MoSi：颗粒表面的沉积以及对复合粉 体团聚的控制。 关键词：包覆；弥散强化；非均匀成核；MoSi2； 中图分类号：TB331 文献标识码：A 文章编号：1001．3814(2008)02．0005．04 Study on Influence Factors of MoSiflCu—base Composite Powder Prepared by Coating Method GUO Tieming ，CHEN Hui ，MA QinL2，ZOU Xinwei ，ZHAO Hongshun (1．State Key Laboratory of Gansu Advanced Non-ferroll~Metal Materials，Lanzhou University of Technology，Lanzhou 730050，China；2．Key Laboratory of Non-ferroll~Metal Alloys，The Ministry of Education，Lanzhou University of Technology，Lanzhou 73O050，China) Abstract：The Cu-coated MoSi2 composite particles were prepared by the method of heterogeneous nucleation． The composite particles were characterized by scanning electron microscopy(SEM)，X-ray diffraction(XRD)，laser grain size analysis and several chemical analysis techniques．Th e coating structure forming mechanism and influence factors were discussed．The results indicate that MoSi2 particles are coated、vim tiny Cu crystalline and distributed homogenously．The solution pH value，grain size and morphology of MoSi2 particles would affect the formation of Cu coating．Acid solution can effectively prevent the composite powder from the reunion，and the coating effect is good． The coating structure depends on the copper deposition on the MoSi2 surface and the control of the composite powders reunion． Key words：coating；dispersion hardening；heterogeneous nucleation；