二氧化钛柱撑蒙脱土的溶剂热合成及光催化活性.pdfVIP

第19卷第1期 化 学 研 究 VoI．19 No．1 2008年3月 CHEMICAL RESEARCH Mat．20o8 二氧化钛柱撑蒙脱土的溶剂热合成及光催化活性 董梦琴，刘建军 ，左胜利，于迎春 (北京化工大学 理学院，北京 100029) 摘 要：以乙醇水溶液为溶剂，以六亚甲基四胺为沉淀剂，以TiCI 为前驱体，通过醇一水溶剂热的方法合成出二 氧化钛柱撑蒙脱土复合纳米光催化剂，通过XRD、BET、AAS等对其物相组成、比表面积及元素含量等进行了表 征．结果表明，复合光催化剂具有良好的介孑L结构，其孑L径分布主要集中在6～】0 nm，且比表面积明显增大．光催 化降解亚甲基蓝活性结果表明，当m(TiO )／m(蒙脱土)=0．2：1时，复合催化剂由于柱化后具有较大的比表面 积、孔容和适当的孔分布而表现出良好的光催化活性． 关键词：溶剂热合成；二氧化钛；蒙脱土；介孔结构；复合光催化剂 中图分类号：0 612．4 文献标识码：A 文章编号：1008—1011(2008)0】一0018—04 Solvothermal Synthesis and Photocatalytic Activities 0f Titania Pillared Montmorillonites DONG Meng—qin，LIU Jian-jun ，ZUO Sheng—li，YU Ying—chun (Faculty of Science，Beijing University of Chemical Technology，Beijing 1 00029，China) Abstract：The nanosized composite photocatalysts of titania pillared montmorillonite were synthesized via solvothermal method by using water and ethanol as solvent，hexamethylene tetramine as precipitant and titanium trichloride as precursor．The phase composition，specific surface area，element content etc were characterized by using XRD，BET and AAS techniques．The composite photocatalysts have created a good mesoporous structure with the distribution of pore diameters centered mainly at 6 to 10 nm，and furthermore，obviously increased their specific surface areas．The results of photocatalytic degradation to methylene blue show that the composite photocatalyst in a ratio of 0．2：1 by weight be— tween TiO2 and montmorillonite has the best photocatalytic activity because of its larger specific surface area，pore volume and suitable pore size distribution． Keywords：solvothermal synthesis；titania；