酸性红g的合成染色分析及废水处理..doc

2011.09.06-2011.09.22 酸性红G的合成、分析、染色及废水处理 刘鸿章（0809401108） 苏州大学材料与化学化工学部2008级应用化学专业 摘要：利用H酸钠盐（1.9935g）和苯胺（0.603g）为原料合成酸性红G，在严格控制温度和pH的情况下，得到酸性红G的产率为93.5%；配制浓度大约为mol/L的酸性红G溶液，利用点硅胶板的方法，测酸性红G的值, 展开剂：正丁醇8mL，乙酸2mL，水10mL；用紫外分光光度计在波长为380nm~580nm范围内测定浓度为3.5mol/L酸性红G的紫外吸收光谱，得到两个最大吸收波长，分别是510nm和531nm，选531nm为准，测浓度为3.5mol/L、7mol/L、1.05mol/L、1.4mol/L、1.75mol/L酸性红G的吸光度，得一直线（工作曲线）；0.4976g羊毛毛线充分洗涤，再配制0.5%的染液，加入硫酸和醋酸得浴比为1：50的染浴，将羊毛毛线放入其中在一定温度时间之内进行染色，洗涤，晾干，得到色泽鲜红的毛线；用二氧化钛光催化降解法处理染色废水，在二氧化钛为0.15g，紫外灯功率为300W，光照距离为10cm，光照时间为20min时去除效果最好，去除率达到98.5%。 关键词：H酸钠盐；酸性红G；硅胶板；二氧化钛；光催化降解 Abstract: Acid Red G is composed of H Acid sodium salt(1.9935g) and aniline(0.603g). The productivity of Acid Red G is 93.5% under the condition of controlled pH and controlled temperature rigidly. Make up Acid Red G solution whose concentration is about mol/L, then use the way of thin layer chromatography to test the of Acid Red G. Developing solvent: normal butanol 8mL ,acetic acid 2mL,water 10mL. The ultraviolet absorption spectrum of Acid Red G whose concentration is 3.5mol/L tested by using ultraviolet spectrophotometer on the wavelength range from 380nm to 580nm. Then it turns out two maximum absorption wavelengths :510nm and 531nm. The absorbance of Acid Red G whose concentration is 3.5mol/L、7mol/L、1.05mol/L、1.4mol/L and 1.75mol/L is tested on the base of 531nm wavelength. Then these statistics form a straight line (called Working Curve). 0.4976g wool is washed fully,then make up 0.5% dye liquor. By adding some sulfuric acid and acetic acid, we can get the dye bath whose bath ratio is 1:50. Then immerse the wool into the dye bath and dye it at the specific time and temperature, wash, and make the wool dry by washing and air drying. At last, you can obtain the wool whose color is bright red. While using titanium dioxide photocatalytic degradation method to treat dyeing wastewater, the removal effect is best and the removal rate reaches to 98.5% under the condition of 0.15g titanium dioxide, the ui