原创力文档cadmium removal from aqueous solution by a tunisian smectitic natural and activated clay thermodynamic study镉去除从水溶液的突尼斯设置自然和活性白土热力学研究.pdfVIP
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cadmium removal from aqueous solution by a tunisian smectitic natural and activated clay thermodynamic study镉去除从水溶液的突尼斯设置自然和活性白土热力学研究
Journal of Encapsulation and Adsorption Sciences, 2011, 1, 65-71
doi:10.4236/jeas.2011.14009 Published Online December 2011 (http://www.SciRP.org/journal/jeas)
Cadmium Removal from Aqueous Solution by a Tunisian
Smectitic Natural and Activated Clay: Thermodynamic Study
L. Khalfa, M. Bagane
Applied Thermodynamics Unit Research , ENIGabes, Zrig Gabes, Tunisia
E-mail : {khalfaleila, drmbag 1420}@yahoo.fr
Received October 25, 2011; revised November 22, 2011; accepted December 4, 2011
Abstract
The removal of heavy metals from industrial waste streams has become one of the most important applica-
tions in wastewater treatment in terms of protecting public health and environment. The recovery of metals
present in the industrial effluents by adsorption onto natural materials constitutes a technological option in-
creasingly studied throughout the world. However, the implementation of such process on an industrial scale
requires the use of adsorbents easily available and inexpensive. Clay in these two forms natural and activated
answers very well to these two requirements. The present research aimed the study of the capacity of fixing
of cadmium present in aqueous solution, by two types of clay: natural and activated. The adsorption capacity
of adsorbent was investigated using batch experiments. The influence of pH, temperature and adsorbent dose
were investigated and the experimental data obtained were evaluated and fitted using adsorbent equilibrium
isotherms. Adsorption isotherms of cadmium onto natural and activated clay were determined and correlated
with common isotherm equations such as the Langmuir and Freundlich models. The Langmuir model agrees
very well with experimental data. The thermodynamic parameters obtained indicated that the adsorption of
cadmium ions onto natural clay was a spontaneous and an
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