effect of scandium doping on the corrosion resistance and mechanical behavior of al-3mg alloy in neutral chloride solutions钪掺杂对al-3mg合金的耐腐蚀性能和力学行为在中性氯化物的解决方案.pdfVIP

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effect of scandium doping on the corrosion resistance and mechanical behavior of al-3mg alloy in neutral chloride solutions钪掺杂对al-3mg合金的耐腐蚀性能和力学行为在中性氯化物的解决方案.pdf

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effect of scandium doping on the corrosion resistance and mechanical behavior of al-3mg alloy in neutral chloride solutions钪掺杂对al-3mg合金的耐腐蚀性能和力学行为在中性氯化物的解决方案

Materials Sciences and Applications, 2011, 2, 244-250 doi:10.4236/msa.2011.24031 Published Online April 2011 (/journal/msa) Effect of Scandium Doping on the Corrosion Resistance and Mechanical Behavior of Al-3Mg Alloy in Neutral Chloride Solutions 1 1 1 2 Zaki Ahmad , Abdul Aleem B. Jabbar , Kachalla Abdullahi , Mohammad Abbas 1Mechanical Engineering Department, King Fahd University of Petroleum Minerals, Dhahran, Saudi Arabia; 2Cathodic protection Engineer, Arabial Petrochemical Company, Jubail, Saudi Arabia. E-mail:{ahmadz, abaleem}@.sa, abbasm@ Received July 24th st th , 2010; revised January 31 , 2011; accepted February 28 , 2011. ABSTRACT Scandium addition significantly alters the corrosion resistance and mechanical strength of Al-3 Mg alloys. The addition of 0.3% - 0.4% scandium with 0.14% zirconium has a beneficial effect on the corrosion resistance of the alloy under smoothly stirred condition. Addition of 0.3% Sc significantly suppresses corrosion under dynamic flow conditions. It also creates an optimal strengthening effect on the alloys. The corrosion resistance is attributed to the strong passive layer of Sc O formed on the ultrafine coherent precipitates of Al Sc. A strong evidence of the pinning of grain bounda- 2 3 3 ries by coherent nano Al3Sc precipitates is responsible for the strengthening effect. Keywords : Corrosion, Polarization, Passive, Pitting, Strengthening Effect, Pinning, Grain Boundaries, Precipitates, Films, Passive Layers 1. Introduction ning of grain boundaries by Al (Sc Zr ) precipitates