effect of agi on conduction mechanism in silver-vanadate superionic glasses美国国际集团对传导机制的影响silver-vanadate超离子导体的眼镜.pdfVIP

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effect of agi on conduction mechanism in silver-vanadate superionic glasses美国国际集团对传导机制的影响silver-vanadate超离子导体的眼镜.pdf

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effect of agi on conduction mechanism in silver-vanadate superionic glasses美国国际集团对传导机制的影响silver-vanadate超离子导体的眼镜

New Journal of Glass and Ceramics, 2011, 1, 112-118 doi:10.4236/njgc.2011.13016 Published Online October 2011 (http://www.SciRP.org/journal/njgc) Effect of AgI on Conduction Mechanism in Silver-Vanadate Superionic Glasses * Poonam Sharma, D. K. Kanchan , Meenakshi Pant, Manish S. Jayswal, Nirali Gondaliya Solid Sate Ionics Glass Research Laboratory, Department of Physics, Faculty of Science, The M.S. University of Baroda, Vado- dara (Gujarat), India. * Email: d_k_kanchan@ Received June 14th, 2011; revised July 27th, 2011; accepted August 9th, 2011. ABSTRACT A quaternary super-ionic glass system xAgI : (95-x) [Ag O:2V O ]: 5TeO where 40 ≤ x ≤65 in steps of 5, has been pre- 2 2 5 2, pared by melt quenching technique. The prepared glass samples are characterized by X-ray, FTIR and DSC studies. As revealed by the FTIR spectra, the oxyanion network is not affected by the addition of AgI. The frequency dependence of the electrical conductivity for various glass compositions at different temperatures has been analyzed in terms of Jon- –7 S/cm to 1.15 scher’s universal power law. The measurements reveal that the conductivity increases from σ = 7.62 × 10 –4 S/cm with increasing AgI content. The temperature dependent conductivity obeys the Arrhenius relationship. The × 10 impedance and modulus studies indicate the non-debye type of the frequency dispersion for all the glass samples. Keywords : Conductivity, Glass Transition Temperature, Infrared Spectra, Impedance, Modulus 1. Introduction to closeness of non-bridging oxygens. The objective o