effect of aging in the structure of silica xerogels with incorporation of extract’s leaves影响衰老的二氧化硅干凝胶的结构与公司提取的树叶.pdfVIP

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effect of aging in the structure of silica xerogels with incorporation of extract’s leaves影响衰老的二氧化硅干凝胶的结构与公司提取的树叶.pdf

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effect of aging in the structure of silica xerogels with incorporation of extract’s leaves影响衰老的二氧化硅干凝胶的结构与公司提取的树叶

New Journal of Glass and Ceramics, 2011, 1, 7-12 7 doi:10.4236/njgc.2011.11002 Published Online April 2011 (http://www.SciRP.org/journal/njgc) Effect of Aging on Chlorophyll Species Embedded in Silica Xerogels Matrix José R. Martínez1*, Erika Espericueta1,2, Gerardo Ortega-Zarzosa1 1Universidad Autónoma de San Luis Potosí, San Luis Potosí, México; 2Centro de Investigación en Materiales Avanzados, Chihuahua, México. Email: flash@fciencias.uaslp.mx Received February 16th, 2011; revised March 30th, 2011; accepted April 6th, 2011. ABSTRACT The spectral fluorescence characteristics of extracts leaves embedded in silica xerogel matrix promoted by aged time was studied. We obtain a higher PSII stability for extract of leaves embedded in xerogel matrix, with concentration of 8 g / 20 ml and water to TEOS molar ratio of 11, which remain bioactive over a very long period of time, whereas for a water to TEOS molar ratio of 5 a blue-shift fluorescence is observed indicating the PSII denaturizing and formation of fluorescing aggregates associated with the activation of carotenoids radicals. Keywords : Fluorescence Spectra, Sol-Gel, Chlorophyll, Extract Leaves, Photosystem II 1. Introduction transfer the energy through photosynthetic apparatus. This situation can be used to take advantage to prepare Sol-gel has even been used to encapsulate and maintain materials based in extract of plants for eventually design the activity of biomolecules. However, currently investi- efficient optical- and electrooptical-based sol-gel encap- gation