原创力文档effect of silicon on the corrosion behavior of powder-processed phosphoric irons硅的腐蚀行为的影响powder-processed磷酸铁.pdfVIP
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effect of silicon on the corrosion behavior of powder-processed phosphoric irons硅的腐蚀行为的影响powder-processed磷酸铁
Journal of Minerals Materials Characterization Engineering , Vol. 9, No.10, pp.855-865, 2010
Printed in the USA. All rights reserved
Effect of Silicon on the Corrosion Behavior of Powder-Processed
Phosphoric Irons
Yashwant Mehta*, Shefali Trivedi, K. Chandra, P.S. Mishra
Indian Institute of Technology, Roorkee- 247667, Uttarakhand, India
* Corresponding Author: yashwant.mehta@
ABSTRACT
The corrosion behaviour of phosphoric irons (i.e. Fe-P alloys containing low phosphorous
in the range 0.1 to 0.7 wt. % ) containing chromium with/without addition of silicon,
prepared by powder forging route was studied in different environments. The various
environments chosen were acidic (0.25 M H2SO4 solution of pH 0.6), neutral/marine (3.5 %
NaCl solution of pH 6.8) and alkaline (0.5M Na CO + 1.0 M NaHCO solution of pH 9.4).
2 3 3
The corrosion studies were conducted using Tafel Extrapolation and Linear Polarization
techniques. The studies compare electrolytic Armco iron with phosphoric irons. It was
observed that silicon improved the resistance to corrosion in all the environments. Corrosion
rates were higher in acid medium, minimal in alkaline medium and low in neutral solution.
Key words : Phosphoric Iron, Corrosion, Powder Metallurgy, Forging, Ancient iron.
1. INTRODUCTION
Corrosion of iron or steel is affected by exposed environment [1]. Corrosion depends on the
composition of the metal/alloy and the environmental conditions. Important electrolyte
variables affecting corrosion of iron are pH, concentration, fluid flow,
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