effect of the pre-treatment severity on the antioxidant properties of ethanol organosolv miscanthus x giganteus lignin预处理的影响严重程度的抗氧化特性的生化乙醇organosolv芒草x竹木质素.pdfVIP
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effect of the pre-treatment severity on the antioxidant properties of ethanol organosolv miscanthus x giganteus lignin预处理的影响严重程度的抗氧化特性的生化乙醇organosolv芒草x竹木质素
Natural Resources, 2012, 3, 29-34 29
/10.4236/nr.2012.32005 Published Online June 2012 (http://www.SciRP.org/journal/nr)
Effect of the Pre-Treatment Severity on the Antioxidant
Properties of Ethanol Organosolv Miscanthus x giganteus
Lignin
1,2 3 3*
Roland El Hage , Dominique Perrin , Nicolas Brosse
1Centre des Matériaux de Grande Diffusion (CMGD), Ecole des Mines d’Alès, France; 2INNOBAT, Cap Alpha, Clapiers, France;
3Laboratoire d’Etude et de Recherche sur le MAteriau Bois, Faculté des Sciences et Techniques, Nancy-Université, Vandœuvre-
lès-Nancy, France.
*
Email: Nicolas.Brosse@lermab.uhp-nancy.fr
Received November 7th, 2011; revised December 29th, 2011; accepted January 8th, 2012
ABSTRACT
The effect of the severity of an organosolv treatment of Miscanthus x giganteus on antioxidant capacity of the obtained
lignin was studied. Four organosolv lignins extracted with different severity conditions were chosen and tested. Results
obtained using the methyl linoleate method have shown a correlation between oxygen uptake index and the combined
severity. It was found that lignin extracted at higher severity pre-treatment and with a higher phenolic hydroxyl content,
lower aliphatic hydroxyl content, molecular weight and polydispersity has the highest antioxidant capacity.
Keywords: Miscanthus x giganteus ; Organosolv Lignin; Antioxidant; Combined Severity; Molecular Weight;
Phenolic and Aliphatic Hydroxyl
1. Introduction lopment in new lignin applications in the fields of fibers,
biodegradable polymers, adhesives... Lignins as well as
The organosolv
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