arsenic speciation in beverages by direct injection-ion chromatography hydride generation atomic fluorescence spectrometry砷物种形成的饮料通过直接injection-ion色谱法氢化物发生原子荧光光谱法.pdfVIP

J ournal of A utomated Methods Management in Chemistry, Vol . 22, No. 2 (March–A pril 2000) pp. 33–39 A rsenic speciation in bev erages by direct injection-ion chrom atographyÐ hydride generation atomic uorescence spectrometry ´ 1 1 generally considered to be non-toxic, are often found in E. Moreno, C. Camara, W .T. Corns, D.W . Bryce and P.B. Stockwell 1 ® sh, seafood and mushrooms. 1 With the total concentration of arsenic in these samples University of Complutense, M adrid, Spain; P S A nalytical, being so low, and the number of individual forms in A rthur House, Cray elds Industrial Estate, M ain Road, which it may be present , it is necessary to develop Orping ton, K ent BR5 3HP , UK . e-mail: psa @psanalytic al. method s with suitably high sensitivity and selectivity to demon.co.uk enable accurate determinati on of each individual arsenic This pape r reports the advantag es of coupling strong anion species. exchang e hig h-perf ormance liquid chromatog raphy hydride g enera- Methods for speciation have to couple the best of separa- tion and atomic uorescence spectrometry f or the speciation of f our tion with the best detection in order to obtain the arsenic species in wine and miner