thermal, spectral, fluorescence, and antimicrobial studies of cobalt, nickel, copper, and zinc complexes derived from 4-[(5-bromo-thiophen-2-ylmethylene)-amino]-3-mercapto-6-methyl-5-oxo-[1,2,4]triazine英文论文.pdfVIP

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thermal, spectral, fluorescence, and antimicrobial studies of cobalt, nickel, copper, and zinc complexes derived from 4-[(5-bromo-thiophen-2-ylmethylene)-amino]-3-mercapto-6-methyl-5-oxo-[1,2,4]triazine英文论文.pdf

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thermal, spectral, fluorescence, and antimicrobial studies of cobalt, nickel, copper, and zinc complexes derived from 4-[(5-bromo-thiophen-2-ylmethylene)-amino]-3-mercapto-6-methyl-5-oxo-[1,2,4]triazine英文论文

Hindawi Publishing Corporation International Journal of Inorganic Chemistry Volume 2012, Article ID 873232, 9 pages doi:10.1155/2012/873232 Research Article Thermal, Spectral, Fluorescence, and Antimicrobial Studies of Cobalt, Nickel, Copper, and Zinc Complexes Derived from 4-[(5-Bromo-thiophen-2-ylmethylene)-amino]- 3-mercapto-6-methyl-5-oxo-[1,2,4]triazine Kiran Singh,1 Yogender Kumar,1 Parvesh Puri,1 Chetan Sharma,2 and Kamal Rai Aneja2 1 Department of Chemistry, Kurukshetra University, Kurukshetra 136119, India 2 Department of Microbiology, Kurukshetra University, Kurukshetra 136119, India Correspondence should be addressed to Kiran Singh, kiransinghkuk@yahoo.co.in Received 3 April 2012; Revised 11 June 2012; Accepted 14 June 2012 Academic Editor: Christopher Allen Copyright © 2012 Kiran Singh et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. A new series of cobalt, nickel, copper, and zinc complexes of bidentate Schiﬀ base derived from the condensation of 5-bro- mothiophene-2-carboxaldehyde with 4-amino-3-mercapto-6-methyl-5-oxo-[1,2,4]triazine were synthesized. Physical (magnetic measurements, molar conductance, TG), spectral (UV-Vis, IR, 1HNMR, ﬂuorescence, ESR), and analytical data have established the structures of synthesized Schiﬀ base and its metal complexes. The presence of coordinated water in metal complexes was conﬁrmed by IR and TG studies. The Schiﬀ base exhibits a strong ﬂuorescence emission, contrast to this partial ﬂuorescence quenching phenomena is observed in its metal complexes. A square planar geometry for Cu(II) and octahedral geometry for Co(II), Ni(II) and Zn(II)