利用静电纺丝法制备掺杂ITO粉末之PVA奈米纤维网-华冈纺织期刊.PDF

JHGT-19.3(124) (2012-09) 華岡紡織期刊 第十九卷 第 三期 ISSN 1025-9678 利用靜電紡絲法製備摻雜ITO 粉末之PVA 奈米纖維網 Nanofibers Prepared from PVA Solution Incorporated with ITO Powder by Electrospinning 陳毓仁 潘毅鈞* 何婷婷** 邢文灝 Y. Z. Chen, Y. J. Pan*, T. T. He**, W. H. Hsing 中國文化大學紡織工程學系 、*亞東技術學院材料與纖維系 、**江南大學生態紡織重點實驗室 Department of Textile Engineering, Chinese Culture University *Department of Material and Fiber, Oriental Institute of Technology **Key Laboratory of Eco-Textiles, Jiangnan University Y. J. Pan, fc003@mail.oit.edu.tw 摘要 本研究利用化學共沉澱法製備出錫氧化物(ITO) ，透過靜電紡絲法製備銦錫氧化物(ITO)/聚乙 烯醇(PVA)奈米纖維，對溶液進行黏度及電導度測試，並使用掃描式電子顯微鏡(SEM)對纖維 表面成形進行觀測。由實驗結果得知，隨著PVA 重量百分比濃度之增加，纖維的靜電紡可紡 性會有著明顯的下降。在PVA 重量百分濃度增加，ITO 摻雜量不變之條件下，紡絲溶液的黏 度及電導度有顯著的提升效果。本實驗所紡製之奈米纖維經文獻比對XRD 之峰型及TEM 之 粉末外觀檢測後證實，粉末確實存在著氧化銦摻雜微量錫之晶格結構，其晶型結構在鐵錳礦 型結構及金剛砂型結構之過渡相存在。 關鍵詞：靜電紡絲、聚乙烯醇、銦錫氧化物、共沉澱法 ABSTRACT In this document, prepared by chemical co-precipitation of indium tin oxide(ITO) through electrospinning to form indium tin oxide(ITO)/ polyvinyl alcohol(PVA) nano-fibers, determined the viscosity and electrical conductivity then observed the fiber surface forming by scanning electron microscope system. This report showed that for the one hand, with the weight percent concentration of the PVA solution increasing , it was obvious inclined for the fibers molding. For another hand, the viscosity and electrical conductivity has increasing with the same doping content