on the determination of trace formaldehyde in urea（在尿素测定微量甲醛）.docVIP

On the determination of trace formaldehyde in urea Abstract: The heating can improve the determination of trace urea formaldehyde sensitivity of the method, the realization of urea in the determination of trace amounts of formaldehyde, raw material testing to meet the daily tasks. Keywords: formaldehyde, trace, urea Urea manufacturers to improve the strength of urea particles added in the production of urea formaldehyde, but the presence of formaldehyde sodium cyanate finished products adversely affected the yield of the Company’s view that even trace amounts of urea formaldehyde products also make the catalyst activity decay, requiring trace of urea formaldehyde measured, and the existing method of GB2440-2001 formaldehyde determination of trace formaldehyde in either quantitative or qualitative aspects are not suitable, while in one experiment found that by heating due to formaldehyde content of the original can low color of the sample is not apparent color, this through a large number of experiments to determine the appropriate analytical methods to meet the testing requirements for raw materials. 1 Experimental 1.1 Instruments and reagents Shimadzu UV-2450 UV spectrophotometer. Sulfuric acid: AR. Chromotropic acid: 1%. Urea: Industrial Formaldehyde working solution: Take 1.5mL in formaldehyde solution 1mg/mL 250mL flask, dilute to the mark, shake, made 3g/mL working solution of formaldehyde. This working fluid instability, to be now with the existing. 1.2 Experimental Methods: A certain amount of standard solution in 100mL flask, add 2.0g of urea formaldehyde-free, additional distilled water to 5mL, shaking the urea dissolved. In another 100mL volumetric flask, add 5mL distilled water as a blank solution in the blank solution samples to be tested and then added 1mL1% chromotropic acid, 10mL of concentrated sulfuric acid, heated in the furnace, when the time began to bubble, continue to remove heat 2min. for 10min after d