溢油指纹GC-MS鉴别地.pdf

Table of Contents Contents Contents (in Chinese)I Contents IV Abatract (in Chinese)VII AbstractVIII Chapter 1 Introduction1 1.1 The Pollution of Spilled Oil1 1.2 The Damage of Spilled Oil 1 1.2.1 The health hazard of spiled oil1 1.2.2 The public security hazard of spilled oil2 1.2.3 The evironment hazard of spilled oil 3 1.3 Oil Properties and the Fate of Spilled Oil5 1.3.1 The compositions and properties of Oil5 1.3.2 The weathered process of spilled oil6 1.4 Oil Analysis and the Spilled Oils Identify7 1.4.1 Fluorescence Spectroscopy Analysis 7 1.4.2 Infrared Spectroscopy Analysis 8 1.4.3 Gas Chromatography Analysis 8 1.4.4 Gas Chromatograph-Mass Spectrometer Analysis 9 1.5 Objective of this Study11 1.6 Structure of this Thesis 11 Chapter 2 Experimental 13 2.1 Materials and Reagents 13 2.2 Weathering Eeperiment and Sample Pretreatment14 2.2.1 Weathering experiment design 14 2.2.2 The improvement of oil pertreatment 14 2.2.3 The preteratment of seawater and semdiment 15 2.3 Instruments and The Condintion of GC-MS16 III Table of Contents 2.3.1 Experimental instruments 16 2.3.2 The condintion of GC-MS 16 2.4 The Qualitative-Quantitative Method17 2.4.1 The anlysis of alkane, pristane, phyane 17 2.4.2 The anlysis of aromatic hydrocarbons 18 2.4.3 The anlysis of sterane sand terpanes 18 2.4.4 The anlysis of diamondioids 18 2.4.5 Semi-Quantitative Analysis 19 2.5 Quality analysis and quality control (QA QC)19