原创力文档influence of methacrylic-acrylic copolymer composition on plasticiser-free optode films for ph sensorsmethacrylic-acrylic共聚物组成对plasticiser-free optode电影ph传感器.pdfVIP
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Sensors 2003, 3, 83-90
sensors
ISSN 1424-8220
© 2003 by MDPI
/sensors
Influence of Methacrylic-Acrylic Copolymer Composition on
Plasticiser-free Optode Films for pH Sensors
*
Lee Yook Heng , Teh Huey Fang, Loh Han Chern and Musa Ahmad
School of Chemical Sciences Food Technology, Faculty of Science and Technology, Universiti
Kebangsaan Malaysia, 43600 Bangi, Selangor, Malaysia.
* Author to whom correspondence should be addressed.
Received: 7 March 2003 / Accepted: 24 March 2003 / Published: 27 March 2003
Abstract: In this work we have examined the use of plasticiser-free polymeric films
incorporating a proton selective chromoionophore for optical pH sensor. Four types of
methacrylic-acrylic copolymers containing different compositions of n-butyl acrylate (nBA)
and methyl methacrylate (MMA) were synthesised for use as optical sensor films. The
copolymers were mixed with appropriate amounts of chromoionophore (ETH5294) and a
lipophilic salt before spin coated on glass slides to form films for the evaluation of pH
response using spectrophotometry. Co-polymer films with high nBA content gave good
response and the response time depended on the film thickness. A preliminary evaluation of
the optical films of high nBA content with pHs from 2 - 14 showed
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