原创力文档nir monitoring of ammonia in anaerobic digesters using a diffuse reflectance probe近红外光谱监测的氨气在厌氧消化器使用漫反射率调查.pdfVIP
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nir monitoring of ammonia in anaerobic digesters using a diffuse reflectance probe近红外光谱监测的氨气在厌氧消化器使用漫反射率调查
Sensors 2012, 12, 2340-2350; doi:10.3390/s120202340
OPEN ACCESS
sensors
ISSN 1424-8220
/journal/sensors
Article
NIR Monitoring of Ammonia in Anaerobic Digesters Using a
Diffuse Reflectance Probe
Chitra S. Raju 1,*, Mette Marie Løkke 2, Sutaryo Sutaryo 1, Alastair J. Ward 1 and
1
Henrik B. Møller
1 Department of Engineering, Aarhus University, Blichers Allé 20, Tjele DK 8830, Denmark;
E-Mails: sutaryo.sutaryo@agrsci.dk (S.S.); alastair.ward@agrsci.dk (A.J.W.);
henrikb.moller@agrsci.dk (H.B.M.)
2 Department of Food Science, Aarhus University, Kirstinebjergvej 10, Årslev DK 5792, Denmark;
E-Mail: mettem.loekke@agrsci.dk
* Author to whom correspondence should be addressed; E-Mail: chitras.raju@agrsci.dk;
Tel.: +45-8715-7874.
Received: 18 January 2012; in revised form: 16 February 2012 / Accepted: 16 February 2012 /
Published: 21 February 2012
Abstract: The feasibility of using a diffuse reflectance probe attached to a near infrared
spectrometer to monitor the total ammonia nitrogen (TAN) content in an anaerobic digester
run on cattle manure was investigated; as a previous study has indicated that this probe can
be easily attached to an anaerobic digester. Multivariate modelling techniques such as partial
least squares regression and interval partial least squares methods were used to build models.
Various data pre-treatments were applied to improve the models. The TAN concentrations
measured were in the range of 1.5 to 5.5 g/L. An R2 of 0.91 with an RMSEP of 0.32 was
obtained implying that
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