photodegradation of acidolysis lignin from bcmp光降解bcmp的酸解木质素.pdfVIP

Molecules 2008, 13, 3129-3139; DOI: 10.3390/molecule OPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article Photodegradation of Acidolysis Lignin from BCMP Mohammad Azadfallah 1,*, Seyed Ahmad Mirshokraei 2 and Ahmad Jahan Latibari 3 1 Wood and Paper Science and Technology Department, University of Tehran, Karaj, Iran 2 Department of Chemistry, Payam-e-Nour University, Tehran, Iran; E-mail: mirshokr@pnu.ac.ir (S- A. M.) 3 Wood and Paper Science and Technology Department, Islamic Azad University, Karaj Branch, Karaj, Iran; E-mail: latibari_24@ (A-J. L.) * Author to whom correspondence should be addressed; E-mail: azadfallah@nrf.ut.ac.ir. Received: 11 November 2008; in revised form: 19 November 2008 / Accepted: 3 December 2008 / Published: 15 December 2008 Abstract: A mild acidic dioxane extraction method was employed to isolate lignin from hardwood bleached chemimechanical pulp (BCMP). The isolated lignin was then purified and undergone elemental analysis. To study the photodegradation behavior, the lignin samples were impregnated onto the Whatman filter papers and irradiated with UV light for 1 various periods. The photolyzed lignin was then recovered and analyzed by H-NMR spectroscopy. Phenylpropane-based formula (C9) of CMP pulp lignin and the photolyzed samples were then established with elemental analysis and 1H-NMR spectroscopy data. The