原创力文档synthesis of star poly(n-vinylcarbazole) by microwave-assisted reversible addition-fragmentation chain transfer polymerization (raft)星的合成聚(n-vinylcarbazole)微波可逆加成断裂链转移聚合(筏).pdfVIP
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synthesis of star poly(n-vinylcarbazole) by microwave-assisted reversible addition-fragmentation chain transfer polymerization (raft)星的合成聚(n-vinylcarbazole)微波可逆加成断裂链转移聚合(筏)
Polymers 2012, 4, 1183-1194; doi:10.3390/polym4021183
OPEN ACCESS
polymers
ISSN 2073-4360
/journal/polymers
Article
Synthesis of Star Poly(N-vinylcarbazole) by Microwave-Assisted
Reversible Addition-Fragmentation Chain Transfer
Polymerization (RAFT)
Mircea Grigoras * and Oana-Iuliana Negru
“P. Poni” Institute of Macromolecular Chemistry, Electroactive Polymers Department, 41A Gr. Ghica
Voda alley, Iasi-700487, Romania; E-Mail: irimia.oana@icmpp.ro
* Author to whom correspondence should be addressed; E-Mail: grim@icmpp.ro;
Tel.: +40-0232-217454; Fax: +40-232-211299.
Received: 27 February 2012; in revised form: 12 April 2012 / Accepted: 4 May 2012 /
Published: 15 May 2012
Abstract: Controlled radical polymerization of N-vinylcarbazole (NVK) via
microwave-assisted reversible addition-fragmentation chain transfer (RAFT) polymerization is
described. As chain transfer agent, 1,3,5-benzyl tri (diethyldithiocarbamate), was used. The
chain transfer agent, containing a 1.3.5-trisubstituted benzene ring as core and three
dithiocarbamate functionalities attached through an intermediate for fragmenting covalent
bonds, led to poly(N-vinylcarbazole) (PVK) with star architecture. Polymerizations were
carried out in 1,4-dioxane as solvent, at 70 °C, and studied for different polymerization
times and monomer/CTA/initiator ratios. The SEC molecular weight curves exhibit a
trimodal distribution, assigned to the linear and star-star coupling polyme
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