原创力文档synthesis of substituted 1,4-diazepines and 1,5-benzodiazepines using an efficient heteropolyacid-catalyzed procedure合成取代1 4-diazepines和1 5-benzodiazepines使用一个高效heteropolyacid-catalyzed过程.pdfVIP
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synthesis of substituted 1,4-diazepines and 1,5-benzodiazepines using an efficient heteropolyacid-catalyzed procedure合成取代1 4-diazepines和1 5-benzodiazepines使用一个高效heteropolyacid-catalyzed过程
Molecules 2011, 16, 92-99; doi:10.3390/molecule
OPEN ACCESS
molecules
ISSN 1420-3049
/journal/molecules
Article
Synthesis of Substituted 1,4-Diazepines and 1,5-Benzodiazepines
Using an Efficient Heteropolyacid-Catalyzed Procedure
Rachedine Kaoua 1, Norah Bennamane 1, Saliha Bakhta 1,2, Sihame Benadji 2,3, Cherifa Rabia 3
and Bellara Nedjar-Kolli 1,*
1 Laboratory of Applied Organic Chemistry, Houari Boumediene University of Sciences and
Technology, BP 31, El-Alia, Bab-Ezzouar, 16111, Algiers, Algeria
2 Center of Research in Physical and Chemical Analysis CRAPC, BP 248, Algiers RP 16004, Algiers,
Algeria
3 Laboratory of Natural Gas, Houari Boumediene University of Sciences and Technology, BP 31,
El-Alia, Bab-Ezzouar 16111, Algiers, Algeria
* Author to whom correspondence should be addressed; E-Mail: bnkollidz@.
Received: 19 November 2010 / Accepted: 11 December 2010 / Published: 28 December 2010
Abstract: An efficient and improved procedure for the synthesis of 1,4-diazepine and 1,5-
benzodiazepine derivatives via the reaction of ketimine intermediates with aldehydes in the
presence of Keggin-type heteropolyacids (HPAs) was developed. High yields and short
reaction times were obtained for both electron-releasing and electron-withdrawing
substituted 1,4-diazepine and 1,5-benzodiazepines derivatives.
Keywords: 1,4-diazepine; 1,5-benzodiazepine; dehydroacetic acid; 1,3-aminomethyl
propane; orthophenylene diamine; heteropolyacids
1. Introduction
Diazepines
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