纳米V2O5新相的制备与表征研究.pdfVIP

第18卷 第2期 材 料 科 学 与 工 程 总第7 0期 Vo 1．1 8No．2 Materials Science＆Engineering June2000 文章墒号：1004-793x(2000)02—0043—03 纳米V：O 新相的制备与表征研究 萋置余 ，三 ，刘皖育 ，俞文海 o ／争 事|} (1．安■机电学院基础部．安鬣 芜湖，2410001 2．中曝科技大学材料科学与工程系，安簟 台肥，230026) l97 【摘 要】 用承解法制备纳米 V 0s，经不同温度退火处理后，用XRD、TEM、DTA、IR实验手 段对纳米V：o 的显微结构进行表征，结果表明，在 290C退火温度以下，形成一种与正交 VzOs不 同的未知新相，该相在 290C附近发生相变，由未知新相转变成V。0s正交相。该新相内吉结构承· 对 x 颗粒 名圮 毒 Investigation of Preparation and Characterization 0f V20s New Phase PAN Deng—ya ，WANG Da—zhi ，NIU Wang—ya ，YU Wen—hai (1．Anhui Institute of Electdea]and Mechanical Engineering，Wllhll Anhul 241000j 2．Depart of Mater．Sole．and Engi．Univ of Scie an d Tech of China，Hefel 230026，Claim ) [Abstract] Nanocrystalline powers V205 were prepared through hydrolysis method．Its microstruc— ture was investigated by XRD、TEM 、IR and DTA．The results show that below 290C temperature，an un— known new phase was formed．and at ahout 290℃ ，the phase transformation took place，the unknown phase was transformed into orthorhomhic phase V O The new phase contained some strueture water OH2， which effeeted notably on X—ray diffraction．Its crystal structure，compared with the otthorhomhic phase， was different，oxygenic atoms being away from V atoms．Its particles were mainly global and average size was 6— 8nm [Key words1 hydrolysis；nanoerystal~ne；V20 5 new phase‘phase transformationI preparation and characterization 法制硫酸、邻苯二甲酸酐与顺丁二烯酐和催化剂，是 引 言 制造陶瓷、红色玻璃的重要原料，也