羧甲基纤维素增强膜的制备及性能-包装工程.pdfVIP

第38 卷 第 17 期 包 装 工 程 2017 年9 月 PACKAGING ENGINEERING ·77 · 包装材料 羧甲基纤维素增强膜的制备及性能 魏占锋，董峰，王小林，马舒慧 （齐齐哈尔大学，齐齐哈尔 161006 ） 摘要： 目的 为了获得一种可用于食品包装的羧甲基纤维素增强膜。方法 以羧甲基纤维素（CMC ）为 成膜基底，甘油为增塑剂，分别将质量分数为 1%，3% ，5%和 10%的纳米纤维素（NCC ）添加到CMC 中，共混流延制备羧甲基纤维素增强膜（CMC-NCC ）。结果 NCC 的加入，提高了CMC 的力学性能和 对水蒸气的阻隔性能，还提高了 CMC 的热性能。FT-IR 分析结果表明，CMC 与NCC 两者间形成了分 子间氢键；XRD 分析结果表明，NCC 可以改变CMC 的结晶排列。当添加质量分数为5%的NCC 时， CMC-NCC 的拉伸强度比纯CMC 膜提高了25.6% ，断裂伸长率降低了21.3% ，透湿量降低了9% ，热稳 定性提高了2% ，透光率维持在87%以上。结论 CMC 增强膜具有力学性能高、阻湿性能好等优点，NCC 提高了CMC 的成膜品质。 关键词：羧甲基纤维素；纳米纤维素；增强膜 中图分类号：TB484.6 文献标识码：A 文章编号： 1001-3563(2017)17-0077-05 Preparation and Properties of Reinforced Carboxymethyl Cellulose Films WEI Zhan-feng, DONG Feng , WANG Xiao-lin, MA Shu-hui (Qiqihar University, Qiqihar 161006, China) ABSTRACT: The work aims to obtain the reinforced carboxymethyl cellulose films (CMC-NCC) for food packaging. With the carboxymethyl cellulose as the formed film base and the glycerol as the plasticizer, NCCs of 1%, 3%, 5% and 10% mass fraction were added into CMC by solution casting and then the CMC-NCC was prepared. The mechanical, moisture barrier and thermal properties of CMC were improved by incorporating the NCC. FT-IR analysis results proved that the intermolecular hydrogen bond was formed between CMC and NCC. XRD analysis results proved that NCC could change the crystallization arrangement of CMC. With the addition of 5% NCC, the tensile strength was increased by 25.6%, the elongation at break was decreased by 21.3%, the water vapor permeability was decreased by 9%, the thermal st