高碱度内配煤含铁团块自还原过程中脱硫和脱磷.pdfVIP

第32卷 第12期 北 京 科 技 大 学 学 报 Vol.32 No.12 2010 年 12 月 Journal of University of Science and Technology Beijing Dec. 2010 高碱度内配煤含铁团块自还原过程中脱硫和脱磷 薛正良摇 赵栋楠摇 杨摇 叠摇 柯摇 超摇 马国军摇 杨摇 福摇 王庆祥 武汉科技大学钢铁冶金及资源利用省部共建教育部重点实验室,武汉430081 摘摇 要摇 以转炉除尘灰、高炉瓦斯灰和硫酸渣为含铁原料,制成CaO/ SiO 值为2郾0、C/ O摩尔比为1郾1~1郾2 的高碱度内配煤 2 含铁团块,在1330~1380益下进行自还原,研究这一过程的脱硫和脱磷规律. 结果表明:(1) 高碱度内配煤含铁团块自还原 过程中,通过还原气化脱硫可去除20% ~40%的硫,其余的硫绝大部分存在于渣中,并通过渣铁分离被去除,总脱硫率高于 97%. (2)过量的CaO可以抑制脉石中的P O 被碳还原,已被还原的磷一部分被新生态的金属铁吸收,另一部分从团块内部 2 5 逸出而去除. 脉石中未被还原的P O 最终可通过渣铁分离被去除,总脱磷率达到50% ~60%. (3) 高碱度内配煤含铁团块 2 5 高温自还原法可制备出低硫、低磷的“纯净冶金属铁粒. 关键词摇 铁;直接还原;脱硫;脱磷 + 分类号摇 TF03 1 Desulfurization and dephosphorization during self鄄reduction of high鄄basicity coal鄄bearing iron oxide briquettes XUE Zheng鄄liang,ZHAODong鄄nan,YANGDie,KE Chao,MA Guo鄄jun,YANGFu,WANG Qing鄄xiang Key LaboratoryoftheMinistryof Educationof ChinaforFerrousMetallurgyandResourcesUtilization,WuhanUniversityof ScienceandTechnology,Wu鄄 han430081,China ABSTRACT摇 High鄄basicity coal鄄bearing iron oxide briquetteswith a CaO/ SiO of 2郾0 and a C/ O molar ratio of 1郾1 to 1郾2,which 2 were produced by BOF steelmaking sludge,BF dedusting ash and pyrite cinder,were self鄄reduced at temperatures from 1330益 to 1380益 to studythephenomenaof desulfurizationanddephosphorization. Duringtheself鄄reduction,thedesulfurizationratioby evapo鄄 rating as COSis20% to40%. Residual sulphurisattachedinslaganditcanbeseparatedfromironnuggets. Thetotaldesulfurization ratio is morethan97%. ExcessiveCaOinhigh鄄basicity coal鄄bearingironoxidebriquettescanrestrainthereactionofphosphorouspen鄄 toxide reduced by carbon. The reducedphosphorou