难熔金属铱与SiC及Y_2O_3的固相反应.pdfVIP

Rare Metal Materials and Engineering Volume 41, Issue 7, July 2012 Online English edition of the Chinese language journal Cite this article as: Rare Metal Materials and Engineering, 2012, 41(7): 1149-1152. ARTICLE Solid State Reaction of Ir with SiC and Ir with Y O 2 3 Hua Yunfeng, Li Zhengxian, Du Jihong, Huang Chunliang Northwest Institute for Nonferrous Metal Research，Xi’an 710016, China Abstract: Solid state reactions between Ir and SiC and between Ir and Y O were studied. The thermodynamics and mechanism of 2 3 solid state reaction were discussed. The results indicate that Ir reacts with SiC at 1000 °C to yield Ir3Si and graphitized carbon. The products of Ir silicide changes from Ir Si and IrSi at 1200 °C to IrSi at 1400 °C. The solid state reaction between Ir and Y O is 3 2 3 thermodynamically favorable above 1800 °C in a reductive carbon atmosphere. The reaction mechanism between Ir and Y O was 2 3 analyzed based on the Engel correlation between electronic configuration and structures of metals and alloy crystal structure. Key words: solid state reaction; Ir; SiC; Y O ; standard enthalpies of formation 2 3 The development of oxidation protective coatings for car- tion (CVD) at 10