异癸醇聚烷氧基醚磷酸酯及其钾盐的合成工艺研讨.pdfVIP

全国第十三次工业表面活性剂研究与开发会议 异癸醇聚烷氧基醚磷酸酯及其钾盐的合成工艺研究 1 2 2 1 韩金芳 李胜兵 张鹏 连工宝 1.飞翔化工 张家港 有限公司 2. 江苏飞翔化工股份有限公司 江苏 张家港 215613 摘要 研究开发了一种具有优良抗静电性和润滑性的特种表面活性剂 分析探讨了以无规 共聚异癸醇聚烷氧基醚 4EO/4PO 为起始剂 五氧化二磷为磷化剂 制备异癸醇聚烷氧 基醚磷酸酯及其钾盐的合成工艺 着重讨论了加料速度 加料温度 配料比 酯化温度 酯化时间 加水量 水解温度及水解时间等因素对反应的影响 确定了较佳的工艺条件 所得产物单 双酯质量比接近 1 1 含固量大于80% 色泽浅 无异臭味 实验稳定性好 在3000 吨/年的中试装置中得到进一步的验证 关键词 磷酸酯 五氧化二磷 酯化 合成 Study on synthesis of isodecanol polyoxyalkylene ether phosphoric ester and its potassium 1 2 2 1 HAN Jin-fang , LI Sheng-bing , ZHANG Peng , LIAN Gong-bao (1. Feixiang Chemicals (Zhangjiagang) Co.,Ltd.; 2.Jiangsu Feixiang Chemical Co., Ltd. Zhangjiagang 215613 Jiangsu, China) Abstract Studied and developped a series of special surfactants with super antistatic property and high lubricity, we investigated the synthesis process that using random isodecanol polyoxyalkylene ether as a staring agent, phosphorus pentoxide as phosphorizing agent, and isodecanol polyoxyalkylene ether phosphoric ester and its potassium was obtained. Specially discussed the effect of feeding time, feeding temperature, feeding ratio, esterification temperature, esterification time, quantity of water added and hydrolysis temperature on reaction process, and the optimum condition was obtained. The ratio of terminal product that mono-phosphate to di- phosphate was about 1:1, solid content was above 80%, light color, odorless and good stability these were obtained further validation in pilotscale experiment of 3000t/a. Key words Phosphate Phosphoric anhydride Esterification Synthesis 醇醚磷酸酯钾盐在磷酸酯类表面活性剂中占有重