氟钛酸改性复合有机硅烷钝化膜及膜层性能研究-表面技术.PDFVIP

摇 第42卷摇 摇 第3 期摇 摇 2013 年6 月 表面技术 摇 摇 摇 Vol.42摇 No.3摇 Jun.2013 SURFACE TECHNOLOGY 摇摇摇 33 氟钛酸改性复合有机硅烷钝化膜及膜层性能研究 1 1 1 2 1 田飘飘 ,张振海 ,徐丽萍 ,杨兴亮 ,张千峰 (1.安徽工业大学 分子工程与应用化学研究所,马鞍山243002; 2.马鞍山钢铁股份有限公司技术中心,马鞍山243000) 摇 摇 [摘摇 要]摇 通过氟钛酸改性KH858+KH580 混合硅烷,配制出无铬钝化液,将其涂覆在热镀锌板上,经烘干、 固化,形成无铬钝化膜。 测定了钝化膜的厚度、附着力和硬度;通过中性盐雾试验,研究了钝化膜的耐化学腐蚀性 能;通过Tafel极化曲线和EIS 图谱,表征了钝化膜的耐电化学腐蚀性能。 结果表明:钝化膜的平均厚度为5.2 滋m,附着力测试的被剥离面积为3%,硬度为3H,均满足国家标准,符合工业生产要求;此外,钝化膜的耐化学腐 蚀和耐电化学腐蚀性能优良,相比于改性前,其性能有较大提高。 [关键词]摇 镀锌钢板;氟钛酸;有机硅烷;钝化膜;耐腐蚀性能 [中图分类号]TG174.46 摇 摇 摇 [文献标识码]A 摇 摇 摇 [文章编号]1001鄄3660(2013)03鄄0033鄄05 The Fluorine Titanate Modified Organic Silanes Passivation Film and Its Properties for Galvanized Steel Surface Coating 1 1 1 2 1 TIAN Piao鄄piao ,ZHANGZhen鄄hai ,XULi鄄ping ,YANGXing鄄liang ,ZHANG Qian鄄feng (1.Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology,Maanshan243002,China; 2.Technique Center,Maanshan Iron Steel Co. ,Ltd. ,Maanshan243000,China) [Abstract]摇 The chrome鄄freepassivationfilmwasmadefrommixed silane KH858 and KH580 modifiedbyfluorinetitan鄄 ate,which wascoated onthe surfaceof hot dip galvanized steelfollowing drying and curing. Thethickness,adhesion,hardness of filmwere tested;The neutral salt spray testing was done to research the resistance to chemical corrosion of the passivefilm. The anti鄄electrochemical resistance of the surface film was characterized by using Tafel polarization curves and electrochemical impedance spectrumtechniques. Theresultsshowedthattheaveragefilmthicknesswas5.2 滋m,thefilmstrippedareawas3% and th