TS1堇青石整体式催化剂的原位合成研究.pdfVIP

TS-1/堇青石整体式催化剂的原位合成 宗 丽，刘 莹，辛 峰 (天津大学化工学院，天津300072，中国) 摘 要：TS-1 分子筛对烃类的选择性氧化反应，如烯烃的环氧化、苯酚的羟基化、氨肟化等具有很高的催化活 性和选择性，是一类绿色反应。但是在使用TS-1 分子筛原粉时，其分离和回收问题一直困扰着工业界。运用水 热合成技术在孔密度为62cell/cm2 的堇青石蜂窝陶瓷载体上原位合成了TS-1 分子筛，并用XRD和SEM等技术对其 进行了表征。探索了适宜的合成路线，操作条件以及配料比，结果表明，经过一次水热合成，堇青石蜂窝载体的 内外表面上可牢固均匀地生长TS-1 分子筛薄膜，而相应的载体增重约为10 ％～15%。尽管载上的晶体粒径较TS-1 粉末大，但晶形完整规则，为正交晶系。 关键词：整体式催化剂；TS-1 分子筛；堇青石；原位合成 in-Situ Synthesis of Titanium Silicalite-1 Monolithic Catalyst ZONG Li ，LIU Ying ，XIN Feng School of Chemical Engineering and Technology ，Tianjin University，Tianjin 300072，China Abstract: Titanium silicalite-1(TS-1) catalytic oxidations is an environment-friendly process because of its particular effectiveness in the oxidation of hydroxylation of benzene and pheno1，epoxidation of alkenes，ammoximation, and so forth. But separation and reuse of TS-1 powder are the main problems with commercial application of low-cost TS-1. In this paper titanium silicalite-1(TS-1) was in-situ synthesized on the surface of honeycomb-shaped cordierite under hydrothermal conditions. Confirmed by XRD, FT-IR and SEM techniques, it has been proved that TS-1 crystals have successfully grown on the surface of cordierite. The conditions, the mixture ratio of the reagents and the process of the preparation were optimized by exploration and practice in the experiment. Finally the weight of the cordierite was increased by 10%-15%. Though the crystal size of TS-1 on the cordierite was bigger than the TS-1 power, the crystal synthesis was uniform and regular vested in the orthorhombic system. Keywords: monolithic catalyst; titanium silicalite-1 molecular sieve; cordierite; in-situ TS-1分子筛由于其独特的催化性能，其制备及应用研究一直是分子筛催化领域中的热点 之一[1] 。TS-1分子筛催化氧化的特点是产物选择性高，反应条件温和，且整个催化氧化过程几乎 无污染物排放，是一