水热法制备钛柱撑蒙脱石及去除砷酸根的作用研究.pdfVIP

水热法制备钛柱撑蒙脱石及去除砷酸根的作用 那平，张帆，赵保林，朱阳明，马海波 天津大学化工学院，天津 300072，中国 摘 要：采用水热法制备了以四氯化钛为前驱物的钛柱撑蒙脱石，通过 X-射线衍射(XRD) ，差热与热重 (DTA-TGA)和透射电子显微镜(TEM)对其结构表征并对其在水体中砷酸根去除作用进行实验对比。结果表明， 水热法制备未经热处理的钛柱撑蒙脱石颗粒均匀，晶型完整，具有良好的热稳定性，由于其比表面积大和表 面羟基含量多等特点对水体中的砷酸根有良好的吸附效果。随着对钛柱撑蒙脱石热处理温度升高，对水体中 砷酸根的吸附能力呈明显下降趋势。 关键词：钛柱撑蒙脱石；水热法；砷酸根去除 Preparation of Titanium Pillared Montmorillonite by Hydrothermal method and Removal of Arsenate NA Ping, ZHANG Fan, ZHAO Bao-lin, ZHU Yang-ming, MA Hai-bo School of Chemical Engineering and Technology，Tianjin University，Tianjin 300072，China Abstract: Titanium pillared montmorillonite with TiCl as the precursors were prepared 4 by hydrothermal method and were characterized using X-Ray Diffraction(XRD), Differential Thermal Analysis-Thermal Gravimetric Analysis(DTA-TGA)and Transmission Electron Microscopy(TEM). The characterization results showed that Ti-MMT(prepared without thermal treatment) had good homogeneous particle size, high crystallization integrity and good thermal stability. TiO2 particles on the surface of Ti-MMT-600(calcined at 600 ℃) became irregular and aggregate. Furthermore, the adsorption of arsenate in water on titanium pillared montmorillonite were conducted. The experiment results indicated that Ti-MMT had effective adsorption of arsenate in water with high specific surface areas and surface Hydroxyl contents. We also found that, as the thermal treatment temperature of titanium pillared montmorillonite increased, the adsorption of arsenate in water obviously decreased. Keywords: titanium pillared montmorillonite; hydrothermal method; removal of arsenate 收稿日期：2006-07-26 作者简介：那平，1966 年，副研究员，Email ：naping@ 主要研究方向为环境水化学及微 量元素物理化学 张帆，1981 年，硕士研究生，Email ：blue