聚乙烯醇二氧化硅杂化膜的制备及性能研讨.pdfVIP

聚乙烯醇/二氧化硅杂化膜的制备及性能研究 1 1 1 2 黄敏 ，王涛 ，曾楚怡 ，李继定 1 2 ( 湘潭大学化工学院, 湖南 湘潭 411105 ; 清华大学化工系膜技术与工程研究中心, 北京 100084) 摘要：以聚乙烯醇(PVA)和正硅酸乙酯(TEOS)为原料,通过溶胶－凝胶（Sol-Gel ）法制备了不同二氧化硅含 量的PVA/SiO2 杂化膜。以水为溶剂，测定了杂化膜的耐溶剂性能。与PVA 膜相比，PVA/SiO2 杂化膜的耐 溶剂性能有显著的提高；杂化膜在环己烷/环己醇/环己酮中的吸附数据证实，杂化膜能优先吸附环己醇和 环己酮且膜材料中的SiO -1 2 能促进环己酮的吸附；FT-IR 结果表明，杂化膜在1099cm 处出现了最大吸收峰， -1 为 Si-O-Si 的非对称伸缩振动吸收峰，及 1068cm 处 Si-O-C 的不对称伸缩振动吸收锋，证实了杂化膜中 Si-O-Si 和Si-O-C 的存在。 关键词：有机无机杂化膜；聚乙烯醇/二氧化硅；溶胶－凝胶 中图分类号：TQ029 文献标识码：A 文章编号： Preparation and Performance of Poly(vinyl alcohol)/Silica Hybrid membranes 1 1 1, * 2 HUANG Min , WANG Tao ，ZENG Chuyi , LI Jiding 1 ( College of Chemical Engineering, Xiangtan University, Xiangtan 411105, Hunan China; 2 Membrane Technology Engineering Research Center, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China) Abstract ：A series of poly(vinyl alcohol)/silica (PVA/SiO ) hybrid films with different silica 2 content were obtained through the sol-gel process using tetraethoxysilane (TEOS).The solvent resistance properties of the hybrid films were also measured using water as the solvent.Compared with the pure PVA film ,the water resistance of these PVA/SiO2 hybrid films improved markedly.The adsorption of cyclohexane/cyclohexanol/cyclohexanone were examined by using PVA/